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影响因子：1.855

DOI码：10.1002/bio.1380

发表刊物：Luminescence

关键字：tadpole shape; isoluminol; luminescent functionality; gold nanomaterials; chemiluminescence

摘要：Iso-luminol functionalized gold nanomaterials were synthesized in high yield by a simple seeding approach, usingthe chemiluminescent reagent iso-luminol as reductant in the presence of HAuCl4, AgNO3and cetyltrimethylammoniumbromide (CTAB). The morphology of as-prepared gold nanoparticles was characterized by transmission electron microscopyand UV–vis spectroscopy, showing that gold nanotadpoles (AuNTps) were obtained. Subsequent experiments revealed thatthe amounts of seed colloids and AgNO3and the concentrations of iso-luminol and CTAB in the growth solution play criticalroles in the formation of well-shaped AuNTps. The surface state of AuNTps was characterized by UV–vis spectroscopy andfluorescence spectroscopy, indicating that iso-luminol and its oxidation product, 4-aminophthalate, coexisted on the surfaceof AuNTps. The CL behaviour was studied by static injection CL experiments, demonstrating that AuNTps were of CL activity.Finally, the growth mechanism of AuNTps was also discussed.

合写作者：田大勇

第一作者：李芳

论文类型：期刊论文

通讯作者：崔华

论文编号：000314658500004

学科门类：理学

文献类型：J

卷号：28

期号：1

页面范围：7-15

ISSN号：1522-7235

是否译文：否

发表时间：2012-01-04

收录刊物：SCI

发布期刊链接：https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/full/10.1002/bio.1380