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    崔华

    • 教授 博士生导师 硕士生导师
    • 教师英文名称:Hua Cui
    • 电子邮箱:
    • 办公地点:环境资源楼-339
    • 联系方式:0551-3600730
    • 学位:博士
    • 2006当选:国家杰出青年科学基金获得者

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    Lucigenin/Co(tryptophan)2 complex bifunctionalized graphene oxide: facile synthesis and unique chemiluminescence

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    DOI码:10.1039/c6tc00072j

    发表刊物:J Mater Chem C

    摘要:In this manuscript, lucigenin (Luc) and Co2+ complex bifunctionalized graphene oxide hybrids (Co(Trp)2/Luc/GO) were synthesized via a facile and simple strategy by virtue of π–π stacking and electrostatic interaction. The as-prepared Co(Trp)2/Luc/GO hybrids exhibited good stability, water-solubility and excellent CL activity when reacted with H2O2, which was more than 30 times higher than Luc/GO. The CL mechanism between Co(Trp)2/Luc/GO and H2O2 has been proposed to be due to the fact that Co2+ could facilitate the formation of HO˙, O2˙− and Co2+–HO2−, accelerating lucigenin CL reaction. Moreover, it was also found that ascorbic acid could directly react with Co(Trp)2/Luc/GO to generate CL emission in the presence of dissolved oxygen. By virtue of Co(Trp)2/Luc/GO as a platform, a sensitive, selective, reagent-less and disposable CL sensor for the detection of ascorbic acid was developed. Ascorbic acid could be determined in the range of 5.0 × 10−7–1.0 × 10−3 M with a detection limit of 0.4 μM. This work reveals that catalyst Co(Trp)2 assembled on the surface of Luc/GO exhibits a unique catalytic effect on lucigenin CL reaction, which provides a new strategy for the synthesis of a lucigenin functionalized nanomaterial with high CL efficiency. The synthesized Co(Trp)2/Luc/GO may find more applications in the development of novel analytical methods.

    第一作者:李琪

    合写作者:李芳,沈雯,刘向阳

    论文类型:期刊论文

    通讯作者:崔华

    论文编号:000374785300014

    学科门类:理学

    文献类型:J

    卷号:4

    期号:16

    页面范围:3477-3484

    ISSN号:2050-7526

    是否译文:

    发表时间:2015-11-30

    收录刊物:SCI

    发布期刊链接:https://pubs.rsc.org/en/content/articlehtml/2016/tc/c6tc00072j