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PSBR: Ǐ'lSv 'lS@~ } Ǐ!nё^\yP[(Co2+0 Cu2+0 Fe3+ etc.),0 2:0 n220 2  7           ?y p@  HC *Group 49#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Toidrs/downrev.xmlDO0~i]F]<od xf7|ٙR4T²x N.8Sp: GXZ&wr\|h򞚃DKPA}HҜ wAdI]cঔ(H+ZF_;i~9wmLJ}}vO_V0bx O@.PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Toidrs/downrev.xmlPKpP ,$D +  H ^A ???Picture 32p@B  H d??Line 33   H `) ??Text Box 35  mOXIDANT  2    H `*) ??Text Box 36`@q jBASE  2    H `!) ??Text Box 37p oluminol" 2   H ^A ???Picture 38` p0 ' H `5) ??Text Box 390   _* 2  B H d??Line 430 p H `3) ??Text Box 44p @  x3-Aminophthalate" 2   H `!) ??Text Box 46 ]+ 2   H `0) ??Text Box 48P!  hn, 2   fBff33nf___PPT10F+,pD' = @B D' = @BA?%,( < +O%,( < +DN ' = @B%(%(D ' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*HD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*HD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*HD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*HD' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*H%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*HD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*HD' = @B%(DI' = @B%(D' =K@BBBBPB0B%(/%(D' =1:Bvisible*o3>+B#style.visibility<*H%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*HD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*HD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H%(DN' =A@BB BB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H%(D' =-}6B!slide(fromLeft)*<3<*H++0+H ++0+H ++0+H ++0+H ++0+H +" @P(  P P ^00) ??Text Box 5"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Ǎdrs/downrev.xmlDj0DnJ#ۄ8QBh(u6X7%IMY3Liى| G06vۗ'`!:K.`>XJwk:mbĆP+2F#c9Mˋ,{M ;zVT7?F@+˭֪~~+!noX>^y;^^5H^@KIPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Ǎdrs/downrev.xmlPKP $ +XP___PPT92* " IQl| (lucigenin)@ 2Cc C*     P ZA ??Object 6"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!* !drs/downrev.xmlDQK@߅c_^H쵈`Xr^6{B|ìsՙ#((6Zϝ$dl756NMF:!j4DZ: q >%˱v)Cx=:j)_~j?:{j_A r _,*PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!* !drs/downrev.xmlPKH`a $@ +dfz P `@2) ??Rectangle 8"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!kUdrs/downrev.xmlDQK0Co.Dс/"mMRlmp[GӉ#E2l+mߞ.nAHVQ,#L`:=YR` >b#Ć\Pl(\6ubӐওYv- iZkw0ōߛ]ٖgck]n_zQyQ?O{UA!GHzI6\PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!kUdrs/downrev.xmlPK  :,$ + lmax = 440 nm(~r) 'lSBR: H2O2 ؏SBR + O2 ؏SBR: sNx ?\x bOW@x PSBR: Ǐ!nё^\yP[ b6RBR: Z{|ir([dkS^ gb6R\O(u0 x0 0 x 0 0 n0                 fp=___PPT10+:DJ' = @B D' = @BA?%,( < +O%,( < +D< ' = @B%(%(D ' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*P%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*PD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*PD' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*P%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*PD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*PD' =A@BBBB0B%(E' => B`BPBpB`B?<*%( /%,( < +D' =1:Bvisible*o3>+B#style.visibility<*P%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*PD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*P+p+0+P ++0+P +" `X}(  X X ^:) ??Text Box 5"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!1drs/downrev.xmlDOO1G&|fH5 1m¶ݴv=N&B>hg 0V>BD+vt`6LjtŊ%  P16Td0 \C6c:}ťkY j6<ヘ|s{U^|7BX6?ӹ[_J;x-"y/& |PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!1drs/downrev.xmlPK`$ +XP___PPT92* 0 Ǐ'lSIxo (peroxyoxalates)@ 2CcC*   x `0  XC *Group 11#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ǝdrs/downrev.xmlDOKk@ M}"RCې`v6dy{W7hqe$AY]ryz<2)r0cm|.B׉.+Ƞؚ8p'6 v!T9^CC5 ·`a_mz>7Icwͽa,;PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!ǝdrs/downrev.xmlPK0` ,$@ + X ZA ??Object 6`0S  X ZA ??Object 7 p  X ZA ??Object 8   X ZA ??Object 9 t  = X `.) ??Text Box 10"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Cdrs/downrev.xmlDj1@CB/E.ҖQR U/q7t,Iw=ox3o2m+Nh Wym\< ;Rp /.Ղ%.I+UCw䘝|x /,̳QZ4/4kC*ȷx7i?>8_V~"QWMW4.1& kPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Cdrs/downrev.xmlPK {w ,$ + ^'lSBR: H2O2 dkS^,gNu1_vSf[SIQ. lmax = 440 nm, 550nm.  2&0 2CKCKC8     fp=___PPT10 +~D\ ' = @B D ' = @BA?%,( < +O%,( < +DN ' = @B%(%(D ' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*XD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*XD' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*X%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*XD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*XD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*XD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*X+p+0+X ++0+X +" &`(  ` ` ^5) ??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDOK1G!EڬڴB;mv37ɒv 8x`:v"0ڶQ ,D;gI̦W;-veIbCT}yh cדMNry=rڦ=-5_o# r?V/z#0i|ZW, `KbT(PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPKZ z$D +XP___PPT92* 6 Wg (1,10-phenanthroline)@ 2CcC*    ` ZA ??Object 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!* drs/downrev.xmlDOMk@)x-bocvLB!wyϙZS#ծ׍@V)n>G GXZ&gr0>>L0k:&>!] rXJdumE LO!ܔ%^CC}%Qb쯟,FS6wKAw rzPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!* drs/downrev.xmlPK|8 $D +A ` ^7) ??Text Box 4"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! F(drs/downrev.xmlDAk1F0B/f(RB]{m܌M$8}j0Y Im[קJ%7 Z-jtc˒Ć(2Ʈ'y15M,rڦ=dsZuϷ*a4" *YY_U%Sl2vN^H^@K_PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! F(drs/downrev.xmlPK0 ,$D + 'lSBR: H2O2 PSBR: Cu2+ Co2+ Pb2+ Fe3+ Ni2+ b6RBR: ˆ}v(NCu2+b_b~TirBO 2CKCK CKCKCKCKCKCKCK~    +       fp=|___PPT10\+LUD' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*`D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*`D' = @B%(D#' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*`%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*`D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*`D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*`D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*`+p+0+` ++0+` +m hh(  h h ^,) ??Text Box 2@@$D +XP___PPT92* & $kpkSIQ (firefly BL)P 2Cc CC*     h ZA ??Object 308 $D +| h ^ 9) ??Text Box 5P ,$D + lmax = 562 nmX 2  h ^;) ??Text Box 6 @7 ,$D + BdkS^͑vRg[a/fATP 10-11~10-14mol" 2 c CKCKCA    fp=y___PPT10Y+D=' = @B + p(  p p  xpC) 0e0e?Rectangle 3@`r NF___PPT9(  &~̃SIQ (bacterial BL)2 2"   p ZA ??Object 4`   p ^`A) ??Text Box 5@ ~؏SW!TvU8hxĞ }"  2 c  " p ^E) ??Text Box 6g  l;NRgir FMN 10-12mol dkS^8^(uNNADHTNADPHՋ 10-15mol~7 2ckckcCp         6 p ^ D) ??Text Box 8`@ Z lmax = 490nmH  2   p ZA ??Object 90 `   fp=y___PPT10Y+D=' = @B + x(  x* x  x0F) 0e0e?Rectangle 21   ^mQ0Sf[SIQvh_      J x  xG) 0e0e?Rectangle 3  ~4RRf[f~S^e IQ1 ϑP[Ns Sf[SIQ:_^   fDW&cC3y___PPT10Y+D=' = @B + (    ^PJ) ??Text Box 3,s zN0Sf[SIQRg"  2 c  x 0  C *Group 13"yN 0`  C *Group 12"0`   ZA ??Object 4`    ^B) ??Text Box 60   u2 2C   ^@) ??Text Box 7`   |hn0 2A   ^`L) ??Text Box 8 `  2C  HA ??Object 9, c  @x   C *Group 31"    \A ??Object 15pK    `H) ??Text Box 16@ ` j   2C 5  `>) ??Text Box 17  dcAR 2CCKC   `P?) ??Text Box 18  zdt0 2CC   \A ??Object 19p0   `@) ??Text Box 20@` ok[R][A]  2C 8  `K) ??Text Box 23P`  O[R]Ǐϑ 0  2 CC*     \A ??Object 27pP!     `K) ??Text Box 28@0`  lk[A]  2C `   `@H) ??Text Box 30 ` ( CA(t) = CA0 e-kt Ic L(t) = jcl u = jcl kCA(t) = jcl k CA0 e-k t 2F0 2CKKCKKCKKCKC  C      C   CKKCKKX f   `p) ??Text Box 32 M   =\{Air(v CA0 T Nv T, FO I 0R Imaxvev T. e-k t:N8^pe. 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YspvECL coS`RP[byP[NuvS zSR:N$N{|: ǏUS͑oS`_vECL(S-route ECL) R - e ! R.+ 5ug'lS R + e ! R. - 5ug؏S R. + + R. - ! R + 1R* 1uWnnmp 1R* ! R + h  SIQǏ z 9,10-NW,\200Hz ]Svel5uMO(1.3 -2.2V vs. SCE)R0R5ug DPA - e ! DPA. + 1.3 V DPA + e ! DPA. - -2.2 V DPA. + + DPA. - ! 1DPA* + DPA 1DPA* ! DPA + h  (  = 512 nm) | Z  Z Z Z " Z=0 Z ccac ccc c ckckckckckckckckck cc.cc ckc kckck ccckckckckckck cccaP         +                     fDW&cC3+#___PPT10.+ SyD' = @B D^' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +-  (  R  ^p??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!8drs/downrev.xmlDAO1&͘x1u`V !#&,x6lmݴă߼Mfmhp;!#W{e\#s+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ + @(    ^r??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!(drs/downrev.xmlDMK1E!<،CelZZKH({3yNi7^&iؙ| xeVNj[ mC`!8K`2a!Ů鼉5K bl C`蹖l)K7 ϳl j:n|[Ut?VBu`?>|_Lv-k l)PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!(drs/downrev.xmlPKp@p$D +<4___PPT9  s|vECLP H d2CCCC *     `o??Rectangle 5"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!mdrs/downrev.xmlDQO0M%M:1adR怐vY/tm_o<[zݰ39_[#~#SZY%`}0rtLt" T!羬HؖLi 1:ť.uçI2k*l饢gsusaHօX>\Sߗ!L4v|9@N@PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!mdrs/downrev.xmlPK0 p$D +<4___PPT9 on a rotating ring (Au)-disc electrode (Au) system disc: O2 OOH- negative pulse ring: OOH- O2- positive pulse LH - L- [ KI dBCKC.CCCKKK!CCCKC   fDW&cC3  ___PPT10 +: yD@ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +"    ` (    \A???Picture 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!^%1drs/downrev.xmlDOˊ0 T|THAƭVq{iM)Mf!I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!~drs/downrev.xmlDMK1EBCx7b38cR "u: $C7^Liٙ| 2`dk'm춯OBD+u\)|6b)Ů鼉 KJbJC`l)K7-ϳl jv>m|u?V[UE?VB3H}WQ/j)\c$dL~PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!~drs/downrev.xmlPKpp$ +<4___PPT9 0 s|vxQWECL S^:gt`I d CCC CC 8      fDW&cC3  ___PPT10 +h HDi ' = @B D$ ' = @BA?%,( < +O%,( < +D[' = @B%(D' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +'!    (  L  ^Pj??Text Box 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!קUdrs/downrev.xmlDMK1E!<،S2Xj?ܸ{NdHb;˹񴷭8p;A]q z"&rZ1UݚԈ q"RWIk͖wrR14R:fmeYwҒqASǏͷE(WW|kn>_i7 =HܧkE-°/ ϧ]0jM1q@~6PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!קUdrs/downrev.xmlPK`p$ +<4___PPT9 \ Ru(bpy)32+vECL Ru(bpy)32+ + e ! Ru(bpy)3+ 5ug؏S Ru(bpy)3 2+ - e ! Ru(bpy)33+ 5ug'lS Ru(bpy)3+ + Ru(bpy)33+ ! Ru(bpy)32+ + Ru(bpy)32+* Ru(bpy)32+* ! Ru(bpy)32+ + h  (  = 620 nm) H0 dn2I d-I0 dF4I0 dnI0 dxCCC K K C  CC K K C C C K K C CC K C K C C C C C K  K C C K K  C K K C C C K K  C K K C K K C C C K K C C C C C C Cb   -  #     fDW&cC3___PPT10+TD' = @B D^' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +#"  (  J  ^py??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDMK1E!)!.V(@VZ8-ܝ}r ˀ]ۆE1[zTr;(ǫ1|_r7[!3D}(WRi<v~;m)PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPK@~$D +JB___PPT9$ L S_SO|-N+T g:_'lSb؏S'`ir(,SeRUSTckb5uS1\SN_0RRu(bpy)32+ vECL0YxQWvRu(bpy)32+ - C2O42- TRu(bpy)32+ - S2O82- SO|eI0 dnC'ckkckkckckk ckkckckkc               \A???Picture 4"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! g=drs/downrev.xmlDOj0x3fZM:cQQ6ժph$Q~_ŕo-+H ke deRp'a7kjCg aȤUCđ`R;pYJ-dž5Tu(8Gqtuc"JM;@c?y{xPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! g=drs/downrev.xmlPKQu ,$D +  ^0|??Text Box 5"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! $drs/downrev.xmlDMK1E!7_F@ˇVk,ox}%M7\c$dLOPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! $drs/downrev.xmlPK p$D +f^___PPT9@8 \ Ru(bpy)32+ - C2O42- qQX[SO|vECL :gt/I dC C K K C K C K K K C cC  c 8#     fDW&cC3|___PPT10\+LUD' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D#' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +"# (  V  dx??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDAK1!fb˶i)JXbfYL$mAo=鼷8c qtõmYc\(|v}5\3tZ$\P#Ny1E_Kඕ,{N ;z6T}oV,t/nU[}.ZnoD>?dV0]`KM g?PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPKm  p$D +<4___PPT9 ` I dC   `m??Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!D@drs/downrev.xmlDQk0|(nN6kEksmMRh=lsbիȺhItadKl yI@V&t:ޗ,@KP@}piIlB-j,Z [zJW}w~͜pO.bЯ_yx3ζE}JYO?eΓm0PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!D@drs/downrev.xmlPK@`$D +XP___PPT92* Ru(bpy)32+ - S2O82- SO|vSIQS^:gt: Ru(bpy)32+ + e ! Ru(bpy)3+ S2O82- + e ! SO42- + SO4.- SO4.- + Ru(bpy)3+ ! Ru(bpy)32+* + SO42- SO4.- + Ru(bpy)32+ ! Ru(bpy)33+ + SO42- Ru(bpy)3+ + Ru(bpy)33+ ! Ru(bpy)32+ + Ru(bpy)32+* Ru(bpy)32+* ! Ru(bpy)32+ + hn~;I0 dI0 dI0 dC K K C K C K K C  c   C K K C C C K K C K C K K C C C C C K K C K K KC K K C K C K K C C C K K C K K C K K C K C K K C C C K K C K K C K K  C K K C C C K K  C K K C CC K K C C C K K C C  C *     fDW&cC3  ___PPT10 +A+Dj ' = @B D% ' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(DZ' = @B%(D' =K@BBBBPB0B%(/%( D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +$ |(    ^Pu??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDJ1EFڌӢulZ"mG^'$NB{93e'A;+~#[;m#zLVb, Pjtg>6,Al(P+8"a:;:o0.=ܴ<ϲnPEȷwVzoBg`?ޔrY0=>r!m2>PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPK'p$D +<4___PPT9  N05uSf[SIQN0 I d2C C   y @0  C (Group 7#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!CXydrs/downrev.xmlDOk@&V"RK"#Lٷ!&w  X-5 E 3KO۷)5VIv|s RTPx_R ndklcR78>B5m LJQaNvwmIa_[+HlwPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!CXydrs/downrev.xmlPKP@0 ,$D +  \A??02Picture 302@ 6   BA ?Object 4 @    ^??Text Box 5 D<4___PPT9 PRECLNhV~gV4 I( d2 CC  ~  ^@s??Text Box 6 0 0 D<4___PPT9 "6Rv5uSf[SIQ`lT~T5ug:yaV2I d2CC  fDW&cC3  ___PPT10 +: yD3 ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D#' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +E%    (  z   x0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!M2drs/downrev.xmlDQK0 mQ1&fksTK >\sf0-f ʩd ,D [gIl sz{1,AlQ9&a:);9o0\yܴ|e`cSƎv^>L]K/J!noHC~|/PYzF0D_M?PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!M2drs/downrev.xmlPKH$ +    V0 5uSf[SIQvyrp> a ca      xp0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!PBdrs/downrev.xmlDN0DHHܨPn6&؎lMz,p|9N,x`[;mV79*e3X../T(w%7 bCAm}!e[6Fgb)M''Yv/ iZks0;=wY33[MP}>?}}W03kUR_M ?PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!PBdrs/downrev.xmlPK`H$ +  upOe^ؚ,~'`V[, NhV{US0 Sf[SIQS^v5uSf[SS[ُNS^(We Nۏ Lc6R0 SǏSbc5uMOc6RS^, 9eU b'`0 IQNuN5ugDя, 9eUNRgcKmvzzc6R0 ՋBRSs:WNu0 l g5uSf[cKm-Nv5uP[r^pb0 Yyir(S TeKm[0 NNSTirS(WECLS^-N_sO(u0 5ughbvalg0 ECLSO|\0 :gt0 T Zccc:c    2    ?    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China28 f( 28f   fDW&cC3  ___PPT10 .+: yD@ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +)(  `(  0   x0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! GOdrs/downrev.xmlDMO1E&摸4(h+q1 wc2m'm⯷q˗r=e2=;Y FqJV¦^] YpKN:,Cl(QBPr lOrS! nP@5HYM|KIʫQz/E* kUa%dlM/~PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! 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S,[Content_Types].xmlN0EH5[8ejE3I,eULDB l,s30jO!Z%q嶄Sv *&{T‘"lˋ)*XB:Ri\05ڣuQh8,P]AO$$J@{k0 s-%r4>^  c瀹UVlM CzA0t!,w3Ȯiڙ 'l"Zb0鯫OPK!֧6 _rels/.relsj0 }Q%v/C/}(h"O = C?hv=Ʌ%[xp{۵_Pѣ<1H0ORBdJE4b$q_6LR7`0̞O,En7Lib/SeеPK!kytheme/theme/themeManager.xml M @}w7c(EbˮCAǠҟ7՛K Y, e.|,H,lxɴIsQ}#Ր ֵ+!,^$j=GW)E+& 8PK!4%4theme/theme/themeOverride1.xmllN0{ߡ+n*e#^*t@6AHwMIIߌ3 + c[0C(  0_ 0  x` 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDN0EH5HlPPJnUUEdSP08w\鼷8Rw nr׵wσil#'0]^L1׾s:n b sKKCзRw"*v n9ʲX`sm,F˷nlV{)rUO z>+QV0?&=z)(HdLAPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPK3H$D +   }# Working curve and detection limit ($ !$$  0  x 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ndrs/downrev.xmlDN1E&CHI)`P\a1}Tz7̗iٙ| 2`d+*l%W \ X(wλX@M]y2F#c%M,rڦ;Z7T}NFA{53$Eaz\VN0+B#style.visibility<*0%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*0D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*0D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*0%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*0D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*0+p+0+0 ++0+0 +QQ, BB,,8B(  8H 8  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!@drs/downrev.xmlDAN0EH$v!ЂBݪ*EdS`O@lФ,G`[q܎2*W+ؽ{qwy\UVjX<`/EZdI)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!,5drs/downrev.xmlDOk@ou% >`mȮIBaf~,׽DK+-+s}ydeR"m=\ש.+Ƞۚ8xwA6 vn*94XrX(mA4 vik}Inǘ O?YL{'\PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!,5drs/downrev.xmlPK`@,$D +*~ '  8C (Group 4"' M~   8C (Group 5"g +8 `P ??Rectangle 6+D<4___PPT9 Sample 4I( dI(dC P ,8 l ??Rectangle 7D<4___PPT9 ` I dC ~ v  8C (Group 8"v )8 ` ??Rectangle 9vD<4___PPT9 SA found (10-7 g/ml) |I( dI(d CKCC C C R *8 n ??Rectangle 10vD<4___PPT9 ` I dC T   8C *Group 11"j '8 b ??Rectangle 12>D<4___PPT9 RSD (%) 4I( dI(d C  R (8 n@ ??Rectangle 13D<4___PPT9 ` I dC    8C *Group 14" %8 b0 ??Rectangle 15D<4___PPT9 SA added (10-7 g/ml) R I( d I(d CKC R &8 n ??Rectangle 16D<4___PPT9 ` I dC X ' v  8C *Group 17"' vn #8 bГ ??Rectangle 18 vD<4___PPT9  SA recovery 4 I( dI(d C  R $8 n ??Rectangle 19' vD<4___PPT9 ` I dC ~ v 8C *Group 20"v !8 b ??Rectangle 21vD<4___PPT9 This method Ref *1 RI( dI(dCKC R "8 n ??Rectangle 22vD<4___PPT9 ` I dC | v'  8C *Group 23"v'  8 b` ??Rectangle 24 v D<4___PPT9 (10-7 g/ml) (%) RI( dI(dCK C R  8 n ??Rectangle 25v' D<4___PPT9 ` I dC R  8C *Group 26"h 8 bP ??Rectangle 27+D<4___PPT9 1 2 3 4I( dI(dC R 8 n ??Rectangle 28D<4___PPT9 ` I dC   8C *Group 29" 8 b0 ??Rectangle 30D<4___PPT9 60.82 0.79 1.78 1.80 2.67 2.64 4I( d%I(d7C7 R 8 n ??Rectangle 31D<4___PPT9 ` I dC X  8C *Group 32"n 8 b ??Rectangle 33>D<4___PPT9  1.1 1.2 0.6 4I( d I(d C  R 8 n ??Rectangle 34D<4___PPT9 ` I dC [  8C *Group 35"q 8 bp ??Rectangle 36D<4___PPT9 1.50 1.50 1.50 4I( d I(dC R 8 n ??Rectangle 37D<4___PPT9 ` I dC | '  8C *Group 38"'  8 b ??Rectangle 39  D<4___PPT9 01.56 103.8 1.50 100.1 1.52 100.8 4I( d!I(d1C1 R 8 n ??Rectangle 40' D<4___PPT9 ` I dC R 8 nP h+??Rectangle 41* D<4___PPT9 ` I dC  8 b ??Rectangle 42"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Fdrs/downrev.xmlDN0EHk*NA}([A]$T(4ۑ6 _;: ILi2h$6֐-ptJf9/FSPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Fdrs/downrev.xmlPK@p$ +<4___PPT9 *Ref: UV-Spectrophotometry>I( dKCA < 8 ` ??Text Box 43@PD<4___PPT9 ` I d2C1 8 `@ ??Text Box 44"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!)jdrs/downrev.xmlDMK1EBCxB7b3i-"pu:I$Bǹ٢7-;Y Im_)Jl% nfXHw[:bĆP+2F#c9M,pڦݏo^k~~ZFm|+SV/&4^/r!.6_PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!)jdrs/downrev.xmlPKp$ +<4___PPT9 >Table 3 The determination of salicylic acid (SA) in bactericidal solution(n=6) LVI d2QCCCV  fDW&cC3IA___PPT10!.+VDQ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-s6Bwipe(left)*<3<*8D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8V%(D' =-s6Bwipe(left)*<3<*8VD' = @B%(D' = @B%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-s6Bwipe(left)*<3<*8D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*8%(D' =-s6Bwipe(left)*<3<*8++0+8 ++0+8 ++0+8 +%-   @ (  @? @  xp 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! sdrs/downrev.xmlDMO0DHkQ"HVUU\*ԏ mMRb;KzhFo&L>4*x% ȖN7R߽=Vc,)Pfvy˕rTP3w`l}%>M+$ɤƇ;ZT~nyx?Or?Z.Rw| iW׿*,{RDhMANPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! sdrs/downrev.xmlPK0H$ +   ] CL mechanism   $ U @  x 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Sadrs/downrev.xmlDKO1&暸'2R.˴:}-0m\|'l1(DQl뤶MZ$DˋVmMuXX8"q<\0r nz>.6?(^o\7.'}h/B\_  >Pw Z/fSPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Sadrs/downrev.xmlPK$ + XP___PPT92* >Who is the emitter? Reduction product of Cerium (IV)? Cerium (III), which is formed by the reduction of cerium (IV), is a well known fluorescent ion and therefore is a possible CL emitter. Cerium (III) lem= 355 nm CL reaction l = 478 nm Cerium (III) is unlikely to be the emitter  & ( (^ &  4   fDW&cC3`X___PPT108.+D' = @B D[' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@%(D' =-s6Bwipe(left)*<3<*@D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@%(D' =-s6Bwipe(left)*<3<*@D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@:%(D' =-s6Bwipe(left)*<3<*@:D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@:%(D' =-s6Bwipe(left)*<3<*@:D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@%(D' =-s6Bwipe(left)*<3<*@D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@%(D' =-s6Bwipe(left)*<3<*@D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*@ %(D' =-s6Bwipe(left)*<3<*@ +p+0+@ ++0+@ +.  H(  HY H  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Z-;drs/downrev.xmlDQO0M5M:1b4$<0Ƌovi z|'l놝yeaLi2]p!f 3Pf&~h[2;X1*.v>JkT&>kMh?y1xzy[zW>t4I>.{d>m4>PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Z-;drs/downrev.xmlPK$ + JB___PPT9$ % Oxidation product of Tween 20? It is postulated that an oxidation product of Tween 20 is an emitter. If the oxidation product is stable, it should be detectable at 478 nm in fluorescent spectra of the CL reaction mixture. However, no peak was observed at 478 nm in the fluorescent spectra. The result indicated that the emitter may be involved in the subsequent reactions or other species may be the emitter. V" ( (y "z  fDW&cC3  ___PPT10 .+DH ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H"%(D' =-s6Bwipe(left)*<3<*H"D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H"%%(D' =-s6Bwipe(left)*<3<*H"%D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*H%%(D' =-s6Bwipe(left)*<3<*H%+8+0+H +/ @ P(  P P  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!i2drs/downrev.xmlDn0ET8jDS B]Bb7C6#ۀ]޹su{v"5ƣ JeZzy75$B)ҞMEuhY_.7i#;I:!Ery\2iÁ;jG-` ~Wk#֟݋7q,P 1_/] (&8.{d>.6PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!i2drs/downrev.xmlPK$ + VN___PPT90( _ Other species? Tween 20 molecules contain several hydroxy group. The oxidation of some polyhydric phenols such as pyrogallol and gallic acid with molecular O2 or H2O2 in alkaline medium were reported to give weak CL. Emission spectra show two peaks with maxima at 475-505 nm and 635 nm. A CL mechanism involving emission from singlet oxygen and intermolecular energy transfer has been proposed:  }( (      fDW&cC3___PPT10.+D2' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*P%(D' =-s6Bwipe(left)*<3<*PD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*P%(D' =-s6Bwipe(left)*<3<*P+8+0+P +0 T L ` X4 (  X  X  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK![(5drs/downrev.xmlDn0D"uW*jR Bcė%#ېЯEb5]yeYLm2]{5$JV iSe!( /8uKdbwNc5\:"\wsKi{*wY&:X}?_'`?2ߧ/] lv=8%K􁜀m)PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-![(5drs/downrev.xmlPKpH$ +  (O2(1Dg))2 2O2(3Sg-) + hn l = 643 nm O2(1Dg) O2(1Sg-) 2O2(3Sg-) + hn l = 478 nm O2(1Dg) O2(1Sg+) + P0 2O2(3Sg-) + 1P* P* P + hn l = 475-505 nm    5   fDW&cC3___PPT10.+Dt' = @B D/' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X*%(D' =-s6Bwipe(left)*<3<*X*D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X+P%(D' =-s6Bwipe(left)*<3<*X+PD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*XP%(D' =-s6Bwipe(left)*<3<*XPD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X%(D' =-s6Bwipe(left)*<3<*XD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*X%(D' =-s6Bwipe(left)*<3<*X+8+0+X +Y 1 QI `1(  ` `  x0 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!G g-drs/downrev.xmlDN0EH5HMǂEJiXtJ}VHK 5vTS[ fS^(;]P|?@0 \}6=7NMnqcd _M ?PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!G g-drs/downrev.xmlPKH$ +  &Therefore, it is likely that the CL reaction formed singlet oxygen 1O2* and the emission was from excited oxygen molecular pairs O2(1Dg) O2(1Sg-).  C;  fDW&cC3___PPT10|.+D' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*`%(D' =-s6Bwipe(left)*<3<*`+8+0+` +k*2   h (  h[  h  x@ 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!9drs/downrev.xmlDMO0DHkQA*mBuAizmoClGۦz,p|9N,x`[;mV7S!U9g\\^̩PdK>c#ĆBPl(\6u{ }#SNY6M-r>7]VϙnP}OW=C{E*dؿw^Bdm2PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!9drs/downrev.xmlPK$ + H@___PPT9" *Pathways The formation of singlet oxygen 1O2* in this reaction may be from three possible routes: Ce4+ + Tween 20 Ce3+ + X X 1O2* + X (1) 1O2* 3O2 + hn X + O2dis (O2__X) 1O2* + X (2) 1O2* 3O2 + hn X + O2dis (1O2--X) * 3O2 + X + hn (3) T  ^  ( ( 1      8       0                         S  fDW&cC3TL___PPT10,.+D' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h %(D' =-s6Bwipe(left)*<3<*h D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h 8%(D' =-s6Bwipe(left)*<3<*h 8D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h8g%(D' =-s6Bwipe(left)*<3<*h8gD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*hg%(D' =-s6Bwipe(left)*<3<*hgD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-s6Bwipe(left)*<3<*hD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h%(D' =-s6Bwipe(left)*<3<*hD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h %(D' =-s6Bwipe(left)*<3<*h D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h "%(D' =-s6Bwipe(left)*<3<*h "D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*h"S%(D' =-s6Bwipe(left)*<3<*h"S+8+0+h +3   p (  p= p  xО 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDn0ETbWBy(`R5|4KBVeyY{ݰ+9_[#e#SZYJy4kHE*6ܗ4mdtEn(I\cm–2E[ ،ݹ{U1x]-ϋ~|γ*x66ۧ} ' ^m4PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPKiH$ +   \Analytical potential $ ~ p  x 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!1drs/downrev.xmlDn0DVVmAU+=pmmlG!=fFocgr^Y#`2΀T֏O|@#\jyBtޅ% hC }ݒF?=Rt fٌkT&=[KtײdyX}ޅ=`bǡíC}H|OSD H~6_PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!1drs/downrev.xmlPK $ + <4___PPT9 ZFor the determination of SA, the interferences from some polyphenols were observed. Is it possible to use the CL reaction for the detection of other compounds? The Effects of some polyphenols and anilines on the CL reaction were examined. 8 Z Z  fDW&cC3___PPT10 .+D^ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*p%(D' =-s6Bwipe(left)*<3<*pD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*pT%(D' =-s6Bwipe(left)*<3<*pTD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*pT%(D' =-s6Bwipe(left)*<3<*pTD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*p%(D' =-s6Bwipe(left)*<3<*p+p+0+p ++0+p +e4 TL x4(  xg x  x 0e0eL?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ݤdrs/downrev.xmlDn0DHu+uNQ(UAQ5] C]Ɨ8%&__v95kʔNǗ0H!7\ s̤̞C(YBq E6dbwNcѕ\:"\|$\ce†֊K XMֻ.US:ί[ɷBg`?>N_ʥY:ίW=@N@PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!ݤdrs/downrev.xmlPKH$ +   5Table 4 The effect of some polyphenols and anilines 6 46 x  xC (Group 3#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!fdrs/downrev.xmlDAk@ay5ZB}&ې]B030Mo*RJ I8\ +ˤN6`=\ש.+Ƞؚ8xA6 vn*94XrX(]At3 >;춯{^vsrǤxo <oi"INrPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!fdrs/downrev.xmlPKp,$D +~  xC (Group 4"~ pT xC (Group 5"pT x `0(??Rectangle 6+ETD<4___PPT9 Organic Compounds* `I( dI(dCKC C P x l(??Rectangle 7pTD<4___PPT9 ` I dC n~ pTT xC (Group 8"pTT x `Џ(??Rectangle 9)TD<4___PPT9 DI TI( dI(dC  R x n(??Rectangle 10pTTD<4___PPT9 ` I dC  T T xC *Group 11"T T x bp(??Rectangle 12 TD<4___PPT9 Organic Compounds* `I( dI(dCKC C R x n (??Rectangle 13T TD<4___PPT9 ` I dC r  T  xC *Group 14" T x b(??Rectangle 15 TD<4___PPT9 DI TI( dI(dC  R x n(??Rectangle 16 TD<4___PPT9 ` I dC w Tp  xC *Group 17"Tp x b(??Rectangle 18+TED<4___PPT9 Salicylic acid PI( dI(dCC C R x n`(??Rectangle 19TpD<4___PPT9 ` I dC m pTT  xC *Group 20"pTT x bP(??Rectangle 21T)D<4___PPT9 +773 PI( dI(dCC C R x n(??Rectangle 22pTTD<4___PPT9 ` I dC y TT   xC *Group 23"TT  x b(??Rectangle 24T D<4___PPT9 Chlorogenic acid PI( dI(dCC C R x n(??Rectangle 25TT D<4___PPT9 ` I dC l  T  xC *Group 26" T x b(??Rectangle 27 TD<4___PPT9 +31 PI( dI(dCC C R x n@(??Rectangle 28 TD<4___PPT9 ` I dC } pb xC *Group 29"pb x b0(??Rectangle 30+EbD<4___PPT9 Sulphosalicylic acid PI( dI(dCC C R x n(??Rectangle 31pbD<4___PPT9 ` I dC m pTb xC *Group 32"pTb x bЄ(??Rectangle 33)bD<4___PPT9 +797 PI( dI(dCC C R x n(??Rectangle 34pTbD<4___PPT9 ` I dC v T b xC *Group 35"T b x bp(??Rectangle 36 bD<4___PPT9 Ascorbic acid PI( dI(d CC C R x n (??Rectangle 37T bD<4___PPT9 ` I dC l  b xC *Group 38" b x b(??Rectangle 39 bD<4___PPT9 +28 PI( dI(dCC C R x n(??Rectangle 40 bD<4___PPT9 ` I dC  bpP  xC *Group 41"bpP  x b(??Rectangle 42+bEP D<4___PPT9 2,4-Dihydroxybenzoic acid PI( dI(dCC C R x n`(??Rectangle 43bpP D<4___PPT9 ` I dC m pbTP  xC *Group 44"pbTP  x bP(??Rectangle 45b)P D<4___PPT9 +557 PI( dI(dCC C R x n(??Rectangle 46pbTP D<4___PPT9 ` I dC z Tb P  xC *Group 47"Tb P  x b}(??Rectangle 48b P D<4___PPT9 2,4-Dinitrophenol PI( dI(dCC C R x n~(??Rectangle 49Tb P D<4___PPT9 ` I dC k  bP  xC *Group 50" bP  x b|(??Rectangle 51 bP D<4___PPT9 ** PI( dI(dCC C R x n@}(??Rectangle 52 bP D<4___PPT9 ` I dC w P p  xC *Group 53"P p  x b0{(??Rectangle 54+P E D<4___PPT9 Phloroglucinol PI( dI(dCC C R x n{(??Rectangle 55P p D<4___PPT9 ` I dC m pP T  xC *Group 56"pP T  ~x by(??Rectangle 57P ) D<4___PPT9 +408 PI( dI(dCC C R x nz(??Rectangle 58pP T D<4___PPT9 ` I dC u TP  xC *Group 59"TP  |x bpx(??Rectangle 60P D<4___PPT9  Benzoic acid P I( dI(d CC C R }x n y(??Rectangle 61TP D<4___PPT9 ` I dC k  P   xC *Group 62" P   zx bw(??Rectangle 63 P  D<4___PPT9 ** PI( dI(dCC C R {x nw(??Rectangle 64 P  D<4___PPT9 ` I dC v  p  xC *Group 65" p  xx bu(??Rectangle 66+ E D<4___PPT9 m-Nitrophenol PI( dI(d CC C R yx n`v(??Rectangle 67 p D<4___PPT9 ` I dC m p T  xC *Group 68"p T  vx bPt(??Rectangle 69 ) D<4___PPT9 +326 PI( dI(dCC C R wx nu(??Rectangle 70p T D<4___PPT9 ` I dC t T  xC *Group 71"T  tx br(??Rectangle 72 D<4___PPT9  Tannic acid P I( dI(d CC C  R ux ns(??Rectangle 73T D<4___PPT9 ` I dC l    xC *Group 74"   rx bq(??Rectangle 75  D<4___PPT9 -88 PI( dI(dCC C R sx n@r(??Rectangle 76  D<4___PPT9 ` I dC s  p~ xC *Group 77" p~ px b0p(??Rectangle 78+ E~D<4___PPT9  Resorcinol P I( dI(d CC C  R qx np(??Rectangle 79 p~D<4___PPT9 ` I dC m p T~ xC *Group 80"p T~ nx bn(??Rectangle 81 )~D<4___PPT9 +296 PI( dI(dCC C R ox no(??Rectangle 82p T~D<4___PPT9 ` I dC t T ~  xC *Group 83"T ~ lx bpm(??Rectangle 84 ~D<4___PPT9  Gallic acid P I( dI(d CC C  R mx n n(??Rectangle 85T ~D<4___PPT9 ` I dC l  ~ !xC *Group 86" ~ jx bl(??Rectangle 87 ~D<4___PPT9 -91 PI( dI(dCC C R kx nl(??Rectangle 88 ~D<4___PPT9 ` I dC ~ ~pl "xC *Group 89"~pl hx bj(??Rectangle 90+~ElD<4___PPT9 p-Hydroxybenzoic acid PI( dI(dCC C R ix n`k(??Rectangle 91~plD<4___PPT9 ` I dC m p~Tl #xC *Group 92"p~Tl fx bPi(??Rectangle 93~)lD<4___PPT9 +276 PI( dI(dCC C R gx nj(??Rectangle 94p~TlD<4___PPT9 ` I dC ~ T~ l $xC *Group 95"T~ l dx bg(??Rectangle 96~ lD<4___PPT9 4-t-Butylpyrocatechol PI( dI(dCC C R ex nh(??Rectangle 97T~ lD<4___PPT9 ` I dC n  ~l %xC *Group 98" ~l bx bf(??Rectangle 99 ~lD<4___PPT9 -92 PI( dI(dCC C T cx p@g(??Rectangle 100 ~lD<4___PPT9 ` I dC | lp& &xC ,Group 101"lp& `x d0e(??Rectangle 102+lE&D<4___PPT9 o-Nitrophenol PI( dI(d CC C T ax pe(??Rectangle 103lp&D<4___PPT9 ` I dC s plT& 'xC ,Group 104"plT& ^x dc(??Rectangle 105l)&D<4___PPT9 +115 PI( dI(dCC C T _x pd(??Rectangle 106plT&D<4___PPT9 ` I dC y Tl & (xC ,Group 107"Tl & \x dpb(??Rectangle 108l &D<4___PPT9  Pyrogallol P I( dI(d CC C  T ]x p c(??Rectangle 109Tl &D<4___PPT9 ` I dC s  l& )xC ,Group 110" l& Zx da(??Rectangle 111 l&D<4___PPT9 -127 PI( dI(dCC C T [x pa(??Rectangle 112 l&D<4___PPT9 ` I dC u &p *xC ,Group 113"&p Xx d_(??Rectangle 114+&ED<4___PPT9 Phenol PI( dI(dCC C T Yx p``(??Rectangle 115&pD<4___PPT9 ` I dC r p&T +xC ,Group 116"p&T Vx dP^(??Rectangle 117&)D<4___PPT9 +96 PI( dI(dCC C T Wx p_(??Rectangle 118p&TD<4___PPT9 ` I dC w T&  ,xC ,Group 119"T&  Tx d\(??Rectangle 120& D<4___PPT9  Dopamine P I( dI(dCC C  T Ux p](??Rectangle 121T& D<4___PPT9 ` I dC r  & -xC ,Group 122" & Rx d[(??Rectangle 123 &D<4___PPT9 -42 PI( dI(dCC C T Sx p@\(??Rectangle 124 &D<4___PPT9 ` I dC p p .xC ,Group 125"p Px d0Z(??Rectangle 126+ED<4___PPT9 Rutin LI dI dCC C T Qx pZ(??Rectangle 127pD<4___PPT9 ` I dC r pT /xC ,Group 128"pT Nx dX(??Rectangle 129)D<4___PPT9 +80 PI( dI(dCC C T Ox pY(??Rectangle 130pTD<4___PPT9 ` I dC v T  0xC ,Group 131"T  Lx dpW(??Rectangle 132 D<4___PPT9 Aniline PI( dI(dCC C  T Mx p X(??Rectangle 133T D<4___PPT9 ` I dC q   1xC ,Group 134"  Jx dV(??Rectangle 135 D<4___PPT9 ** PI( dI(dCC C T Kx pV(??Rectangle 136 D<4___PPT9 ` I dC w p 2xC ,Group 137"p Hx dT(??Rectangle 138+ED<4___PPT9  Catechol P I( dI(dCC C  T Ix p`U(??Rectangle 139pD<4___PPT9 ` I dC r pT 3xC ,Group 140"pT Fx dPS(??Rectangle 141)D<4___PPT9 +73 PI( dI(dCC C T Gx pT(??Rectangle 142pTD<4___PPT9 ` I dC  T  4xC ,Group 143"T  Dx dQ(??Rectangle 144 D<4___PPT9 p-Phenylendiamine PI( dI(dCC C T Ex pR(??Rectangle 145T D<4___PPT9 ` I dC q   5xC ,Group 146"  Bx dP(??Rectangle 147 D<4___PPT9 ** PI( dI(dCC C T Cx p@Q(??Rectangle 148 D<4___PPT9 ` I dC  p 6xC ,Group 149"p @x d0O(??Rectangle 150+ED<4___PPT9 3,4-Dihydroxybenzoic acid PI( dI(dCC C T Ax pO(??Rectangle 151pD<4___PPT9 ` I dC r pT 7xC ,Group 152"pT >x dM(??Rectangle 153)D<4___PPT9 +69 PI( dI(dCC C T ?x pN(??Rectangle 154pTD<4___PPT9 ` I dC b T  8xC ,Group 155"T t +B#style.visibility<*x6%(D' =-s6Bwipe(left)*<3<*x6D' = @B%(D' = @B%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*x%(D' =-s6Bwipe(left)*<3<*x+8+0+x +l5 dd PPd(     xP(0e0eL?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ftdrs/downrev.xmlDAO1&fLIWY({!viGvxMb8Sw Gr׍ߞ@DF\(b~}5BmZ$*0]!e Y#ߑKPKOpqMƥ U/`9^~fhrͰ`dR+I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Tdrs/downrev.xmlDAk@B &f[zA-g}k}P87LM#z\eYA<@VW\(:?-A8L n`zdj;/DKQA}J mwAdWH঑Q" VJli[R^Fǀf}}~΋>& O Y$+ W@~PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Tdrs/downrev.xmlPK,$D +%Y~ t  C (Group 4"t t~ " C (Group 5"" O `P(??Rectangle 6+"D<4___PPT9 Organic Compounds PI( dI(dCC C P P l(??Rectangle 7"D<4___PPT9 ` I dC y~ " C (Group 8"" M `(??Rectangle 9"D<4___PPT9 Linear range (ng/ml) PI( dI(dCC C R N n(??Rectangle 10"D<4___PPT9 ` I dC |  " C *Group 11" " K b(??Rectangle 12>\ "D<4___PPT9 Regression equation PI( dI(dCC C R L n@(??Rectangle 13 "D<4___PPT9 ` I dC   "  C *Group 14" " I b0(??Rectangle 15 "D<4___PPT9 Correlation Coefficient l I( d I(d CC CC C R J n(??Rectangle 16 "D<4___PPT9 ` I dC   "  C *Group 17" " G bа(??Rectangle 18* "D<4___PPT9 Detection Limit (ng/ml)  I( dI(d CC CC CC C R H n(??Rectangle 19 "D<4___PPT9 ` I dC w "*  C *Group 20""* E bp(??Rectangle 21+"*D<4___PPT9 Salicylic acid PI( dI(dCC C R F n (??Rectangle 22"*D<4___PPT9 ` I dC q "*  C *Group 23""* C b(??Rectangle 24"*D<4___PPT9  4 ~ 1100 P I( dI(dCC C  R D n(??Rectangle 25"*D<4___PPT9 ` I dC  " *  C *Group 26"" * A b(??Rectangle 27>"\ *D<4___PPT9 (lgDI=6.65 + 0.75lgC I( dI(dCCCC  R B n`(??Rectangle 28" *D<4___PPT9 ` I dC o  " * C *Group 29" " * ? bP(??Rectangle 30 " *D<4___PPT9 0.9983 PI( dI(dCC C R @ n(??Rectangle 31 " *D<4___PPT9 ` I dC l  "* C *Group 32" "* = b(??Rectangle 33* "*D<4___PPT9 2.5 PI( dI(dCC C R > n(??Rectangle 34 "*D<4___PPT9 ` I dC } *~ C *Group 35"*~ ; b(??Rectangle 36+*~D<4___PPT9 Sulphosalicylic acid PI( dI(dCC C R < n@(??Rectangle 37*~D<4___PPT9 ` I dC r *~ C *Group 38"*~ 9 b0(??Rectangle 39*~D<4___PPT9  40 ~ 8000 P I( dI(d CC C  R : n(??Rectangle 40*~D<4___PPT9 ` I dC  * ~ C *Group 41"* ~ 7 bХ(??Rectangle 42>*\ ~D<4___PPT9 $lgDI=6.73+0.75lgC rI( dI(dC C  R 8 n(??Rectangle 43* ~D<4___PPT9 ` I dC o  * ~ C *Group 44" * ~ 5 bp(??Rectangle 45 * ~D<4___PPT9 0.9987 PI( dI(dCC C R 6 n (??Rectangle 46 * ~D<4___PPT9 ` I dC l  *~ C *Group 47" *~ 3 b(??Rectangle 48* *~D<4___PPT9 7.5 PI( dI(dCC C R 4 n(??Rectangle 49 *~D<4___PPT9 ` I dC  ~l  C *Group 50"~l  1 b(??Rectangle 51+~l D<4___PPT9 2,4-Dihydroxybenzoic acid NI dI(dCC C R 2 n`(??Rectangle 52~l D<4___PPT9 ` I dC r ~l  C *Group 53"~l  / bP(??Rectangle 54~l D<4___PPT9  12 ~ 6200 P I( dI(d CC C  R 0 n(??Rectangle 55~l D<4___PPT9 ` I dC  ~ l  C *Group 56"~ l  - b(??Rectangle 57>~\ l D<4___PPT9 $lgDI=5.84+0.66lgC rI( dI(dC C  R . n(??Rectangle 58~ l D<4___PPT9 ` I dC o  ~ l  C *Group 59" ~ l  + b(??Rectangle 60 ~ l D<4___PPT9 0.9946 PI( dI(dCC C R , n@(??Rectangle 61 ~ l D<4___PPT9 ` I dC l  ~l  C *Group 62" ~l  ) b(??Rectangle 63* ~l D<4___PPT9 9.0 PI( dI(dCC C R * n (??Rectangle 64 ~l D<4___PPT9 ` I dC w l t  C *Group 65"l t  ' b`(??Rectangle 66+l t D<4___PPT9 Phloroglucinol PI( dI(dCC C R ( n0(??Rectangle 67l t D<4___PPT9 ` I dC q l t  C *Group 68"l t  % b(??Rectangle 69l t D<4___PPT9  63 ~1000 P I( dI(dCC C  R & n(??Rectangle 70l t D<4___PPT9 ` I dC  l t  C *Group 71"l t  # b(??Rectangle 72>l \ t D<4___PPT9 $lgDI=6.42+0.76lgC xI( dI(dC C  R $ n(??Rectangle 73l t D<4___PPT9 ` I dC o  l t  C *Group 74" l t  ! b(??Rectangle 75 l t D<4___PPT9 0.9960 PI( dI(dCC C R " n@(??Rectangle 76 l t D<4___PPT9 ` I dC k  l t  C *Group 77" l t   b(??Rectangle 78* l t D<4___PPT9 48 PI( dI(dCC C R   n(??Rectangle 79 l t D<4___PPT9 ` I dC R  nК(h+??Rectangle 80w D<4___PPT9 ` I dC  fDW&cC3___PPT10.+fD%' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*Q%(D' =-s6Bwipe(left)*<3<*QD' = @B%(D' = @B%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-s6Bwipe(left)*<3<*+8+0+ +&B6 AA CCA(    ^(??Text Box 2@0D<4___PPT9 N. 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Ce(SO4)2 810-5mol/l(0.075mol/l H2SO4 AmRv CH3OH:H2O:CH3COOH Am 1.0 ml/min T)n-20 9%pI d2 C&C   ;             fDW&cC38 2*` (  F   x0f0e0e?Rectangle 2P0   z&AmRl\5uSf[SIQb6RlKm[ Nz }" g    xf0e0e?Rectangle 3t0$b >6___PPT9 zECLb6RRRf[f~ FI-ECLS^agNOS $NyRu(bpy)32+ SIQSO|agN NVR_e z r^pb[ Rg^(u ECLb6R:gtxvz \F vPZ!CKK"Cp           fDW&cC389 %88 ::8(  R   ~f0e0e?Rectangle 2G    FI- ECLAm ,  G$  s6v   C (Group 3" \  rPf ??Rectangle 4 D<4___PPT9 f&I( dGb  # 2@ABhCpDE FQRUVXjJ?hp@~Freeform 5  b  # 2@ABCDE FQRUVXjJ?@Freeform 6Q, b  # 2@ABC8DE FQRUVXjJ?88@ S Freeform 7 ,  2  NfjJ?Rectangle 8ez D<4___PPT9 ` I dC tB   DjJ?Line 9vB   FjJ?Line 10vB   FjJ?Line 11 W |B   LjJ?Line 12 vB   FjJ?Line 13% 3 3|B  LjJ?Line 14. !U  `f?Text Box 15jeD<4___PPT9 qPBS&I(dG |B  LjJ?Line 16 0 vB  FjJ?Line 17P  vB B FjJ?Line 18V T   ``f?Text Box 19D<4___PPT9  TPrA or C2O42-I(d GOGOOG vB  FjJ?Line 20 B  X>?Line 21zo |B B LjJ?Line 22 , \  ffjJ?Text Box 23 h D D<4___PPT9 rCell&I(dG vB  FjJ?Line 24 A     C *Group 25"T @ *2 8 F)fjJ?Oval 26 D<4___PPT9 ` I dC vB 9 FjJ?Line 27 vB : FjJ?Line 28`` vB  FjJ?Line 29S    J0/ C *Group 30"^  vB 5 FjJ?Line 31J88vB 6 FjJ?Line 320/vB 7 FjJ?Line 33J0J/B  RV?Line 34t k X  `f?Text Box 35U D<4___PPT9 tSample&I(dG e  fpfjJ?Text Box 36, S" D<4___PPT9 { Luminometer( I8dT G  V  ` f?Text Box 37b+6D<4___PPT9 rI /O&I(dG Y   `f?Text Box 389D<4___PPT9 uA/D D/A&I(dG W ! `f?Text Box 39@ , >  D<4___PPT9 sWaste&I(dG T " `0f?Text Box 40D<4___PPT9 pWE&I(dG T # `f?Text Box 41 D<4___PPT9 pCE&I(dG T $ ` f?Text Box 42Q O D<4___PPT9 pRE&I(dG vB % FjJ?Line 43 vB & FjJ?Line 44   ' `@!f?Text Box 45| D<4___PPT9  Ru(bpy)32+f I(dGOOG   ( `!f?Text Box 46j/ h$ D<4___PPT9 H2OPI(dGOG U ) `"f?Text Box 47D<4___PPT9 q2.0&I(dG U * `P#f?Text Box 48D<4___PPT9 q2.0&I(dG U + `$f?Text Box 49 D<4___PPT9 q2.0&I(dG d , `$f?Text Box 50_ D<4___PPT9 Peristaltic pump(IhdG X - ``%f?Text Box 51)z &U D<4___PPT9 tml/min&I(dG V . `&f?Text Box 52'Q  D<4___PPT9 rI /O&I(dG h / f&fjJ?Text Box 53 pD<4___PPT9 ~ Potentiostat* IxdX G  b 0 fp'fjJ?Text Box 54SX D<4___PPT9 xComputer( I8dT G  a 1 l (fjJ?Text Box 55k H V$ D<4___PPT9 qPMT&I(dG B 2 X>?Line 56 q g B 3 X>?Line 57. o. c U 4 `(f?Text Box 588  D<4___PPT9 q1.9&I(dG  fDW&cC3: D< $(  t  C +f?Rectangle 2jz~    FI  ECLB\5u`l~g 0 g    pv p  C (Group 3"V  r@,f??Rectangle 4p D<4___PPT9 ` I dC   HA# ?Object 5_4  fDW&cC3>;  (     x/f0e0e?Rectangle 2   HRu(bpy)32+ /TPrA/ Nz } FI  ECLRRf[f~ v% g o o g 8      `A$ ? ?Object 308  fDW&cC3< ZR :(  B   xP.f0e0e?Rectangle 2,T   vFI-ECLagNOS"  g     x1f0e0e?Rectangle 3ci b >6___PPT9 bAm 5ug5uMO Ru(bpy)32+ TPrA bC2O42- vSm^ PBSSm^ pH 2 vKZCKKCKCKKCp          fDW&cC3 = * "  (  N   x3f0e0e?Rectangle 2p   PBSSm^vq_T2 G GB  v 0`{ C (Group 3"p0  A%? ?*gh-1 bPicture 4*gh-1 b0`{G  F05f?Text Box 5P` ; D<4___PPT9 }a4I( dCC E  F5f?Text Box 6` { D<4___PPT9 {b2I( dCC   ^4f??Text Box 7'8D<4___PPT9 Effect of PBS concentrations on DI of the two FI-ECL systems aRu(bpy)32+ - TPrA  Nz }SO|, Ru(bpy)32+: 2.010-5 mol/L, TPrA: 1.010-4 mol/L, PBS: 0.1 mol/L ( pH 8) , Nz }: 1.010-6 mol/L bRu(bpy)32+- C2O42 Nz }SO|, Ru(bpy)32+: 2.010-5 mol/L, C2O42-: 5.010-4 mol/L, PBS: 0.2 mol/L ( pH 5.4), Nz }: 210-6 mol/L; 5ug5uMO=1.05 V (vs. Ag/AgCl)UI d2    I    .  7    -     ?    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ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸѧıPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸšѧص »ѧPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸ ġ »ѧصPowerPoint ʾĸiA novel method for determination of salicylic acid by use of Ce(IV)-Tween 20 chemiluminescence reaction PowerPoint ʾĸPowerPoint ʾĸFlow injection system$ Working curve and detection limit  Application CL mechanism PowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸAnalytical potential6Table 4 The effect of some polyphenols and anilines QTable 5 Parameters of regression equations and detection limits for polyphenols PowerPoint ʾĸPowerPoint ʾĸ'ע»ѧƷⶨ FI- ECL· FI C ECLؽṹ /Ru(bpy)32+ /TPrA/ FI C ECLѧ FI-ECLŻPBSŨȵӰpHӰ زⶨĻع鷽ƷصIJⶨ PowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸ Thank you!  õ4Ƕ OLE   õƬE_xgHCuiHCui  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