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DPA + h  (  = 512nm) | Z  Z Z Z " Z<0 Z ccac ccc c ckckckckckckckckck cc.cc ckc kckck ccckckckckckck cccaP         +                     fDW&cC3+#___PPT10.+ SyD' = @B D^' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +"1 p(  R  ^@U ??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!8drs/downrev.xmlDAO1&͘x1u`V !#&,x6lmݴă߼Mfmhp;!#W{e\#s+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +" vnV(    ^O ??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!(drs/downrev.xmlDMK1E!<،CelZZKH({3yNi7^&iؙ| xeVNj[ mC`!8K`2a!Ů鼉5K bl C`蹖l)K7 ϳl j:n|[Ut?VBu`?>|_Lv-k l)PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!(drs/downrev.xmlPKp@p$D -<4___PPT9  s|vECLP H d2CCCC *   _  `X ??Rectangle 5"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!cadrs/downrev.xmlDJ@E0"B ϤUÚlbwNSR9"\wr$ 5񡡞Gnx~|t,z[ ^^w LɮE8C~6\PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!cadrs/downrev.xmlPK0 p$D -<4___PPT9 non a rotating ring (Au)-disc electrode (Au) system disc: OOH- negative pulse ring: OOH- O2- positive pulse LH - L- [ KI dDC8CCCKKK!CCCKC   fDW&cC3  ___PPT10 +: yD@ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +"&    (    \A???Picture 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!^%1drs/downrev.xmlDOˊ0 T|THAƭVq{iM)Mf!I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!~drs/downrev.xmlDMK1EBCx7b38cR "u: $C7^Liٙ| 2`dk'm춯OBD+u\)|6b)Ů鼉 KJbJC`l)K7-ϳl jv>m|u?V[UE?VB3H}WQ/j)\c$dL~PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!~drs/downrev.xmlPKpp$ -<4___PPT9 0 s|vxQWECL S^:gt`I d CCC CC 8      fDW&cC3  ___PPT10 +h HDi ' = @B D$ ' = @BA?%,( < +O%,( < +D[' = @B%(D' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +"5    (  V  ^PW ??Text Box 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Zkdrs/downrev.xmlDMk1ECxB7(CԂ? 9 N!Iu.^iؙ| 2`d+'|_S`!8K`1ͰbtŚ%  P1Rd0\K6uG }ͥKY j:~|3{Ur!] ,RAEIO߮C$/ %d |~PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Zkdrs/downrev.xmlPK`= p$ -<4___PPT9 f Ru(bpy)32+vECL Ru(bpy)32+ + e ! 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Ru(bpy)32+ + h n (  = 620 nm) H0 dn2I d+I0 dF3I0 dnI0 dxCCC K K C CC K K C C C K K C CC K C K C C C C C K  K C C K K  C K K C C C K K  C K K C K K C C C K K C CC C C C Cb   +  #     fDW&cC3___PPT10+TD' = @B D^' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+8+0+ +"# (  J  ^K ??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDMK1E!)!.V(@VZ8-ܝ}r ˀ]ۆE1[zTr;(ǫ1|_r7[!3D}(WRi<v~;m)PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPK@~$D -JB___PPT9$ L S_SO|-N+T g:_'lSb؏S'`ir(,SeRUSTckb5uS1\SN_0RRu(bpy)32+ vECL0YxQWvRu(bpy)32+ - C2O42- TRu(bpy)32+ - S2O82- SO|eI0 dnC'ckkckkckckk ckkckckkc               \A???Picture 4"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! g=drs/downrev.xmlDOj0x3fZM:cQQ6ժph$Q~_ŕo-+H ke deRp'a7kjCg aȤUCđ`R;pYJ-dž5Tu(8Gqtuc"JM;@c?y{xPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! g=drs/downrev.xmlPKQu ,$D -  ^X ??Text Box 5"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! chdrs/downrev.xmlDMO1E&晸1a$#{Li;oB7ܜ55;Ynl餶s,DkgIGC,;ױb bCTMy( ]אMy1E_qyqڦ =)*?F@Ӎ֪~xdK!#Hm̿p^{ C$/ %d |PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! chdrs/downrev.xmlPK p$D -f^___PPT9@8 R Ru(bpy)32+ - C2O42- qQX[SO|vECL :gt*I d C C K K C K C K K K C cC  c 8     fDW&cC3|___PPT10\+LUD' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D#' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +"& (  V  dR ??Text Box 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDAK1!fb˶i)JXbfYL$mAo=鼷8c qtõmYc\(|v}5\3tZ$\P#Ny1E_Kඕ,{N ;z6T}oV,t/nU[}.ZnoD>?dV0]`KM g?PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPKm  p$D -<4___PPT9 ` I dC   `V ??Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!D@drs/downrev.xmlDQk0|(nN6kEksmMRh=lsbիȺhItadKl yI@V&t:ޗ,@KP@}piIlB-j,Z [zJW}w~͜pO.bЯ_yx3ζE}JYO?eΓm0PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!D@drs/downrev.xmlPK@`$D -XP___PPT92* Ru(bpy)32+ - S2O82- SO|vSIQS^:gt: Ru(bpy)32+ + e ! 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8RgSf[^(u N0 AmRl\Sf[SIQRg Hua Cui*, Shifeng Li, Xiangqin Lin Chemiluminescence of Ce (IV) and surfactant Tween 20 Analyst, 2001, 126, 553 Hua Cui*, Shifeng Li, Feng Li, Yugang Sun, Xiangqin Lin A novel chemiluminescent method for determination of salicylic acid in bactericidal solutions Analytical and Bioanalytical Chemistry, 2002 372 601 ( 2( 2&( ZP( 2;( Z` 26( 2  5 0` 4T :      @` fDW&cC3___PPT10+ SyD' = @B D^' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<* %(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<* D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<* +8+0+  +"V   0 (     xZ 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! drs/downrev.xmlDN0IxxN ! nyzX'k;ʆOo\|'ߟou.|mqLiem*#0Hl!WZ ̤̎.P(1>C*6ܗ4mDvNctEnx$36qAaKiM.~owX>ܞO\OU4MoOW@N@ _PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! drs/downrev.xmlPKPPH$D - !@ hA novel method for determination of salicylic acid by use of Ce(IV)-Tween 20 chemiluminescence reaction  i g$i    x0S 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Ɲdrs/downrev.xmlDOK@Ga؍nK-z0 45M=ox?l1N b띂I\u1yG a1?2ֆ,Ɖ1`1Xn;yeSiu`{CgmgPdf|zJD1?]V[nW Ghu1QPPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Ɲdrs/downrev.xmlPK 0H$D - "@ Hua Cui, Shifeng Li, Feng Li, Yugang Sun, Xiangqin Lin Department of Chemistry, University of Science & Technology of China, Hefei, Anhui 230026, P.R. China28 f( 28f   fDW&cC3  ___PPT10 .+: yD@ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +) P(  0   xT 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!5wdrs/downrev.xmlDj0Bo\LF %j,HJ+rh,1E; Je:fy75$DVMMUX_>ܷ=i;IlkƐNqzy\2iǑ{jwQur>b~&>= P^T2e1́mNd>SnPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!5wdrs/downrev.xmlPK $D - H@___PPT9" Ce(IV) + Tween 20 + H+ CL salicylic acid enhanced the CL H $ $C   tA!??DFTPLSF1Picture 3DFTPLSF1"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!18drs/downrev.xmlDO[k0~?3eh:bQDe0 oؖ5'%{3ŝ,+$ s+.kˤ# 3m!"PABI m#w`R;|pSacC J7۴[޷Y~sJD6[x2??PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!18drs/downrev.xmlPKpl ,$D -f  ^c ??Text Box 4p p$D -<4___PPT9 ` I d2Cf  ^h ??Text Box 5p p$D -<4___PPT9 ` I d2C  ^ \ ??Text Box 6"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!,L}drs/downrev.xmlDOK1G!ج,ڴXAJx6LwdI7xmŅB4)xg U^W+<>L@DF\)b~{3RZ$%*hRX5d1}G.9:`䶕yҢqi^g ߎ|\ɏRw:LŤqz;LAA L PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!,L}drs/downrev.xmlPK0  p$D -<4___PPT9 Fig.1 Chemiluminescence spectra (a) Ce4+ + Tween 20 ; (b) Ce4+ + Tween 20 + salicylic acid lmax = 478 nm!I dI( d&I dI d'CKCKCC Cm  fDW&cC3-%___PPT10.+ncDm' = @B D(' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*B%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*BD' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*BD' = @B%(D#' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*+p+0+ ++0+ +"B, p$s(  $" $0 s A" ?5%8c8c    ?Object 2#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ӡdrs/downrev.xmlDj@a8$ZLDJH!sLR3gBfj;B?/[ 7\mYA<@V\*86s#kl,;9X壧 Sm{ޗ"KQA}J銊 mwAdWJaM#'QH5 [zu᧷|؞_QyX/Ax &Q<X@PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!ӡdrs/downrev.xmlPKP'  $ - ff $ ^k ??Text Box 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!gdrs/downrev.xmlDMK1E!̀Զ}{"Z$L&ҝ욎ذD*Ʈ<Ԋ ȦnoxJp"AmӃŽf(VaZEM}%M?}¯L,ρ;C$/ &ݤ | PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!gdrs/downrev.xmlPK0  p$ -<4___PPT9 rFig.2 Kinetic Curves Tween 20: 8%(v/v) SA: 4.010-7 g/mL Ce4+: 810-5 mol/L (0.1 mol/L H2SO4) (a): Ce4+ + Tween 20 (b): Ce4+ + Tween 20 + salicylic acid fI( dI dI d |I d3CCK CKCCKCKCK CKCK'C  fDW&cC3G?___PPT10.+ByD' = @B Dz' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-s6Bwipe(left)*<3<*$D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-s6Bwipe(left)*<3<*$D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$*%(D' =-s6Bwipe(left)*<3<*$*D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$*>%(D' =-s6Bwipe(left)*<3<*$*>D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$>S%(D' =-s6Bwipe(left)*<3<*$>SD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$Sm%(D' =-s6Bwipe(left)*<3<*$SmD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$m%(D' =-s6Bwipe(left)*<3<*$mD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-s6Bwipe(left)*<3<*$D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*$%(D' =-s6Bwipe(left)*<3<*$+8+0+$ +"9 ,,$$,,(  ,> ,  xc 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!H ?drs/downrev.xmlDAN0E5HZ( u*" xjb;ئI9=v9[Fӱ:+~#8Z%> Ypdt鴋%  1d0\O6eG tzť!M,{[4|~2_zsTowc,ϵR>UIy0Ƿoe!nRPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!H ?drs/downrev.xmlPKWH$ -   ]Flow injection system $ 1 ,  x0i 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!/drs/downrev.xmlDn0D֭] RV a%$؎l__Eb5H#[;m#a[fBDs$\)jyB-鼉 K %az;o0<^t<"M-R}ܜζSVד5T3HC1/g $db2΁?;U!nRPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!/drs/downrev.xmlPKH$ -  PFig. 3  "w  ]  ,C (Group 4#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!gG_drs/downrev.xmlD͊0¼C4((" .͵-67ɴb`Ƿ-5 G 3K\/+ˤE6 m;>S\v *()]VA75q1lr¸$C5 ʞQpN|^vIg]_L|O`~PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!gG_drs/downrev.xmlPKx,$D -. , Hg ?Rectangle 5QJD<4___PPT9 b"I(dC nB , >?Line 6 @@nB , >?Line 7 R"2 , >`o ?Oval 8UD<4___PPT9 ` I dC "2  , >^ ?Oval 9D<4___PPT9 ` I dC $2  , @ r ?Oval 10"D<4___PPT9 ` I dC vB  , F?Line 11 pB  , @?Line 12#pB  , @?Line 13]]B , R?Line 14--pB , @?Line 15vB , F-?Line 16/v/pB , @?Line 17!^pB , @?Line 18 -9-vB , F?Line 19:+:vB , F-?Line 20RoRpB , @?Line 21-YHY$2 , @i ?Oval 22Z#D<4___PPT9 ` I dC $2 , @Pm ?Oval 23D<4___PPT9 ` I dC $2 , @n ?Oval 24kD<4___PPT9 ` I dC B , R?Line 25%%V , Hpq ?Text Box 26i?D<4___PPT9  Sample2I(dC C  F , He ?Text Box 27 ;uCD<4___PPT9 z Tween 20"I(dC  l , Hl ?Text Box 28x D<4___PPT9  H2OTI(dC C K C  m , Hp ?Text Box 29l )D<4___PPT9  Ce4+TI(dC C K C  F , H0^ ?Text Box 306] bYD<4___PPT9 z ml/min"I(dC  9 , Hn ?Text Box 31_D<4___PPT9 m2.9"I(dC  X  , Hp ?Text Box 32 YD<4___PPT9 " Peristaltic pump"#I(d#C # 9 !, Hr ?Text Box 33rzD<4___PPT9 m2.9"I(dC  ? ", Hs ?Text Box 344D<4___PPT9 s Flow cell" I(d C   ; #, H0t ?Text Box 350 D<4___PPT9 oWaste"I(dC  9 $, Ht ?Text Box 36D<4___PPT9 m2.9"I(dC   fDW&cC3 z ___PPT10Z .+եED ' = @B D} ' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-s6Bwipe(left)*<3<*,D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =-s6Bwipe(left)*<3<*,D' = @B%(D#' = @B%(D' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*,%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*,D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*,+p+0+, ++0+, +" ia4I(  4_ 4  xy 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!6ndrs/downrev.xmlDN1E&CLi!q6h@>9}LVfm\ޜ3_aWvVh(-m%} Ypnr+ 6(A朇R0t-ԝ7SW7 τpM[Zk*?_F*[g9`b'}UcW %!i6vz}Z1D`M?PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!6ndrs/downrev.xmlPK3H$D -   }# Working curve and detection limit ($ !$$  4  x} 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ddrs/downrev.xmlDN0DHHܨ U%M/ܶ61v۔ћӱ0 `dkm$f,D ;gI‰gS̕;ڒذ!G m}y[2F'c1M3!AmC==TV{#a5R6~ Ea,XtzW2q7mNU!nR>PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!ddrs/downrev.xmlPKp$D - ___PPT9d\ 6jRegression equation lgDI = 6.65 + 0.75lgc (r=0.9983) Linear range 4.010-9 ~ 1.110-6 g/ml Detection limit 2.510-9 g/ml (S/N=3) Standard deviation: 0.85% (n=11) %     #               #  fDW&cC3  ___PPT10 .+: yD@ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*4D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*4D' = @B%(D0' = @B%(D' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*4%(D' =+4 8?dCB0-#ppt_w/2BCB#ppt_xB*Y3>B ppt_x<*4D' =+4 8?\CB#ppt_yBCB#ppt_yB*Y3>B ppt_y<*4+p+0+4 ++0+4 +"IQ BB,,<xB(  <I <  xy 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!9B_drs/downrev.xmlDn0DV8DA)!J\PxIRb;[zьiŅ|hU0% ȖN7R|{Vc,)RnveǕrTP3w`l}%>M+$yjhUSy}tO)~FRcίV Mi6q||(u*/PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!9B_drs/downrev.xmlPK%H$ -   g Application (  $ /y *  <C (Group 3#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!|<drs/downrev.xmlDO0 [UC5ԅۣy4,,xf7|ٙR4T² N.8Ss~OA8L `cm'j>.AU"Ks2"}u&umRh, rhSz??]jo~^/!&z_jS^+DdPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!|<drs/downrev.xmlPK`@,$D -)~ '  <C (Group 4"' M~   <C (Group 5"g +< `@ ??Rectangle 6+D<4___PPT9 Sample 4I( dI(dC P ,< l ??Rectangle 7D<4___PPT9 ` I dC ~ v  <C (Group 8"v )< ` ??Rectangle 9vD<4___PPT9 SA found (10-7 g/ml) nI( dI(d CKCC C R *< n ??Rectangle 10vD<4___PPT9 ` I dC T   <C *Group 11"j '< b ??Rectangle 12>D<4___PPT9 RSD (%) 4I( dI(d C  R (< n0 ??Rectangle 13D<4___PPT9 ` I dC    <C *Group 14" %< b  ??Rectangle 15D<4___PPT9 SA added (10-7 g/ml) R I( d I(d CKC R &< nЈ ??Rectangle 16D<4___PPT9 ` I dC X ' v  <C *Group 17"' vn #< b ??Rectangle 18 vD<4___PPT9  SA recovery 4 I( dI(d C  R $< np ??Rectangle 19' vD<4___PPT9 ` I dC ~ v <C *Group 20"v !< b@v ??Rectangle 21vD<4___PPT9 This method Ref *1 RI( dI(dCKC R "< n ??Rectangle 22vD<4___PPT9 ` I dC | v'  <C *Group 23"v'  < bP ??Rectangle 24 v D<4___PPT9 (10-7 g/ml) (%) RI( dI(dCK C R  < n ??Rectangle 25v' D<4___PPT9 ` I dC R  <C *Group 26"h < b } ??Rectangle 27+D<4___PPT9 1 2 3 4I( dI(dC R < nu ??Rectangle 28D<4___PPT9 ` I dC   <C *Group 29" < b@ ??Rectangle 30D<4___PPT9 60.82 0.79 1.78 1.80 2.67 2.64 4I( d%I(d7C7 R < n ??Rectangle 31D<4___PPT9 ` I dC X  <C *Group 32"n < b ??Rectangle 33>D<4___PPT9  1.1 1.2 0.6 4I( d I(d C  R < nS ??Rectangle 34D<4___PPT9 ` I dC [  <C *Group 35"q < b` ??Rectangle 36D<4___PPT9 1.50 1.50 1.50 4I( d I(dC R < n ??Rectangle 37D<4___PPT9 ` I dC | '  <C *Group 38"'  < b0 ??Rectangle 39  D<4___PPT9 01.56 103.8 1.50 100.1 1.52 100.8 4I( d!I(d1C1 R < nPx ??Rectangle 40' D<4___PPT9 ` I dC R < nw h+??Rectangle 41* D<4___PPT9 ` I dC  < bv ??Rectangle 42"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! $drs/downrev.xmlDQO0M%M:ЈN Q| f]ְK[毷AOw-Vn؅WN`dJ+w7|@# a]-03]P1>Eumʹ/k'%uCa$5\SyZW6w{S[ù8TBq~ӇS+QR,?N߆S2C Q7_PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! $drs/downrev.xmlPK@p$ -<4___PPT9 *Ref: UV-Spectrophotometry>I( dKCA < < ` ??Text Box 43@PD<4___PPT9 ` I d2C1 < `{ ??Text Box 44"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!@rdrs/downrev.xmlDMK1EBCx7b3i-"pu:I$op˽˙-zӲ0eNj?> Ypjtg.6,Al(P+8"a:;8o0.=ܴ<ϲ 7mzPJQ}}&[Vk嚿o)H}?LYR&Hv8;\*C$/ &ݤ |PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!@rdrs/downrev.xmlPKp$ -<4___PPT9 >Table 3 The determination of salicylic acid (SA) in bactericidal solution(n=6) LVI d2QCCCV  fDW&cC3IA___PPT10!.+VDQ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-s6Bwipe(left)*<3<*<D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<V%(D' =-s6Bwipe(left)*<3<*<VD' = @B%(D' = @B%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-s6Bwipe(left)*<3<*<D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*<%(D' =-s6Bwipe(left)*<3<*<++0+< ++0+< ++0+< +"%    D (  D? D  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!)drs/downrev.xmlDMO0DHkQ!VUU\*ԏ %)IX8|8Sw 'r׭k/wO "yG .a>btq#澔2ֆ,ƉɥEN14Rv2ϲGiu`OKC*X`V>7rUm Fx/_TYQ9Z$TA~PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!)drs/downrev.xmlPK0H$ -   ] CL mechanism   $ U D  x 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDN0DHuQTB$ԭx>K4E+ (b lvj,u*PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPK$ - XP___PPT92* >Who is the emitter? Reduction product of Cerium (IV)? Cerium (III), which is formed by the reduction of cerium (IV), is a well known fluorescent ion and therefore is a possible CL emitter. Cerium (III) lem= 355 nm CL reaction l = 478 nm Cerium (III) is unlikely to be the emitter  & ( (^ &  4   fDW&cC3`X___PPT108.+D' = @B D[' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-s6Bwipe(left)*<3<*DD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-s6Bwipe(left)*<3<*DD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D:%(D' =-s6Bwipe(left)*<3<*D:D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D:%(D' =-s6Bwipe(left)*<3<*D:D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-s6Bwipe(left)*<3<*DD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D%(D' =-s6Bwipe(left)*<3<*DD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*D %(D' =-s6Bwipe(left)*<3<*D +p+0+D ++0+D +"  L(  LZ L  x` 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!cdrs/downrev.xmlDAO@&͘pmKPYѠp;fw_ƃ߼-VnمWH 02~4[kH<7 ̥MA}Y&.W icۑ:!FWs鰏p,I\2qg-ਲ~kI E,.di::)YKԍ?PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!cdrs/downrev.xmlPK$ - JB___PPT9$ % Oxidation product of Tween 20? It is postulated that an oxidation product of Tween 20 is an emitter. If the oxidation product is stable, it should be detectable at 478 nm in fluorescent spectra of the CL reaction mixture. However, no peak was observed at 478 nm in the fluorescent spectra. The result indicated that the emitter may be involved in the subsequent reactions or other species may be the emitter. V" ( (y "z  fDW&cC3  ___PPT10 .+DH ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*L"%(D' =-s6Bwipe(left)*<3<*L"D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*L"%%(D' =-s6Bwipe(left)*<3<*L"%D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*L%%(D' =-s6Bwipe(left)*<3<*L%+8+0+L +"  0T(  T T  xP 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Zdrs/downrev.xmlDN0EH5H쨝U*] 4&؎luz,ѹL lO>hg%l딶u"Z$Hӓ)VlMUXP>Ʊ<= 7y1!K!nAmsC#=~vFFk'a55G)XSx~ Q/JBY\">7^C$/! fݬ |PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Zdrs/downrev.xmlPK$ - VN___PPT90( _ Other species? Tween 20 molecules contain several hydroxy group. The oxidation of some polyhydric phenols such as pyrogallol and gallic acid with molecular O2 or H2O2 in alkaline medium were reported to give weak CL. Emission spectra show two peaks with maxima at 475-505 nm and 635 nm. A CL mechanism involving emission from singlet oxygen and intermolecular energy transfer has been proposed:  }( (      fDW&cC3___PPT10.+D2' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*T%(D' =-s6Bwipe(left)*<3<*TD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*T%(D' =-s6Bwipe(left)*<3<*T+8+0+T +"  T L P\4 (  \  \  x` 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!wAdrs/downrev.xmlDj0D).ƍJKX:n[%I~}Er gMvVt"ҶVOBDs$\(rq{3Bt^dž% Jhc Cݒ0q=7S W7τȹAmC=T'#a ջ0cMX1mTi.Z"y I0&U_PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!wAdrs/downrev.xmlPKpH$ -  (O2(1Dg))2 2O2(3Sg-) + hn l = 643 nm O2(1Dg) O2(1Sg-) 2O2(3Sg-) + hn l = 478 nm O2(1Dg) O2(1Sg+) + P0 2O2(3Sg-) + 1P* P* P + hn l = 475-505 nm    5   fDW&cC3___PPT10.+Dt' = @B D/' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*\*%(D' =-s6Bwipe(left)*<3<*\*D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*\+P%(D' =-s6Bwipe(left)*<3<*\+PD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*\P%(D' =-s6Bwipe(left)*<3<*\PD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*\%(D' =-s6Bwipe(left)*<3<*\D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*\%(D' =-s6Bwipe(left)*<3<*\+8+0+\ +"]   QIpd1(  d d  xp 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK! y?drs/downrev.xmlDMO0DHkQ'6ԭ|8Tq$ۑmz,p|9NɇY$ArMVc,)8Qbv-ZD 9*h\P5d0L\O6v{ rᦓYK P>6(_3[X~>@0??ہ_ԛV4=| L^AQPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-! y?drs/downrev.xmlPKH$ -  &Therefore, it is likely that the CL reaction formed singlet oxygen 1O2* and the emission was from excited oxygen molecular pairs O2(1Dg) O2(1Sg-).  C;  fDW&cC3___PPT10|.+D' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*d%(D' =-s6Bwipe(left)*<3<*d+8+0+d +"o*   l (  l[  l  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!2 drs/downrev.xmlDMO1E&摸)`kca1}T-0m\ޜ3_c' x`:^(V;`1yG .a]ͱJ:mR2)nb\>XL9 B̸EC=ZU3re,6 I,ѐ?"+QZb:/]0Ę((ȂY7_PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!2 drs/downrev.xmlPK$ - H@___PPT9" *Pathways The formation of singlet oxygen 1O2* in this reaction may be from three possible routes: Ce4+ + Tween 20 Ce3+ + X X 1O2* + X (1) 1O2* 3O2 + hn X + O2dis (O2__X) 1O2* + X (2) 1O2* 3O2 + hn X + O2dis (1O2--X) * 3O2 + X + hn (3) T  ^  ( ( 1      8       0                         S  fDW&cC3TL___PPT10,.+D' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l %(D' =-s6Bwipe(left)*<3<*l D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l 8%(D' =-s6Bwipe(left)*<3<*l 8D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l8g%(D' =-s6Bwipe(left)*<3<*l8gD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*lg%(D' =-s6Bwipe(left)*<3<*lgD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l%(D' =-s6Bwipe(left)*<3<*lD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l%(D' =-s6Bwipe(left)*<3<*lD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l %(D' =-s6Bwipe(left)*<3<*l D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l "%(D' =-s6Bwipe(left)*<3<*l "D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*l"S%(D' =-s6Bwipe(left)*<3<*l"S+8+0+l +"   t (  t< t  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!(0drs/downrev.xmlDN0 HCd$n,]TMSUD/k MRv<=}ַLg N| xݹVn "&t{H"lW+,ݞ· XPHC8;`1Z ̳AZ08Pi8|Yۼ|yMuLNVNۛi"єbXUk9ϜuNϗ=DA_XUAPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!(0drs/downrev.xmlPK iH$ -   \Analytical potential $ ~ t  x 0e0e?Rectangle 3"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Idrs/downrev.xmlDn0D"VRES Bh1KoK$nc; 1|}-tnYћ/ىWȧ02ʴvq4{kH<,ws,MEmhY_.7iS;I:!E=sʤz*vxL&?w!&q ,P qx+/)Hs`)Y$T/PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Idrs/downrev.xmlPK $ - <4___PPT9 ZFor the determination of SA, the interferences from some polyphenols were observed. Is it possible to use the CL reaction for the detection of other compounds? The Effects of some polyphenols and anilines on the CL reaction were examined. 8 Z Z  fDW&cC3___PPT10 .+D^ ' = @B D ' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*t%(D' =-s6Bwipe(left)*<3<*tD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*tT%(D' =-s6Bwipe(left)*<3<*tTD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*tT%(D' =-s6Bwipe(left)*<3<*tTD' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*t%(D' =-s6Bwipe(left)*<3<*t+p+0+t ++0+t +"k VN|6(  |h |  x 0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!DsKdrs/downrev.xmlDN0EH5H쨃"֭Pb=q S$)_,Gwt=`֑G0S$/BDq$\(b~{3\nŊ% 9J19d0\K6e' t+},{k4T~Xc>`b#ݰ4}WT$1z9Zm1D`MPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!DsKdrs/downrev.xmlPKH$ -   5Table 4 The effect of some polyphenols and anilines 6 46 y  |C (Group 3#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ydrs/downrev.xmlDOk@~MbM]E"GoCvM  3_-5 F 3KO_S#k,9X.^_jڣEKQA}J鲂 wAdK`঒IMB5 nǻQaśvw?I[V+Hd<PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!ydrs/downrev.xmlPKp,$D -~  |C (Group 4"~ pT |C (Group 5"pT | ``9t??Rectangle 6+ETD<4___PPT9 Organic Compounds* `I( dI(dCKC C P | l:t??Rectangle 7pTD<4___PPT9 ` I dC n~ pTT |C (Group 8"pTT | `8t??Rectangle 9)TD<4___PPT9 DI TI( dI(dC  R | n8t??Rectangle 10pTTD<4___PPT9 ` I dC  T T |C *Group 11"T T | b6t??Rectangle 12 TD<4___PPT9 Organic Compounds* `I( dI(dCKC C R | nP7t??Rectangle 13T TD<4___PPT9 ` I dC r  T  |C *Group 14" T | b@5t??Rectangle 15 TD<4___PPT9 DI TI( dI(dC  R | n5t??Rectangle 16 TD<4___PPT9 ` I dC w Tp  |C *Group 17"Tp | b3t??Rectangle 18+TED<4___PPT9 Salicylic acid PI( dI(dCC C R | n4t??Rectangle 19TpD<4___PPT9 ` I dC m pTT  |C *Group 20"pTT | b2t??Rectangle 21T)D<4___PPT9 +773 PI( dI(dCC C R | n03t??Rectangle 22pTTD<4___PPT9 ` I dC y TT   |C *Group 23"TT  | b 1t??Rectangle 24T D<4___PPT9 Chlorogenic acid PI( dI(dCC C R | n1t??Rectangle 25TT D<4___PPT9 ` I dC l  T  |C *Group 26" T | b/t??Rectangle 27 TD<4___PPT9 +31 PI( dI(dCC C R | np0t??Rectangle 28 TD<4___PPT9 ` I dC } pb |C *Group 29"pb | b`.t??Rectangle 30+EbD<4___PPT9 Sulphosalicylic acid PI( dI(dCC C R | n/t??Rectangle 31pbD<4___PPT9 ` I dC m pTb |C *Group 32"pTb | b-t??Rectangle 33)bD<4___PPT9 +797 PI( dI(dCC C R | n-t??Rectangle 34pTbD<4___PPT9 ` I dC v T b |C *Group 35"T b | b+t??Rectangle 36 bD<4___PPT9 Ascorbic acid PI( dI(d CC C R | nP,t??Rectangle 37T bD<4___PPT9 ` I dC l  b |C *Group 38" b | b@*t??Rectangle 39 bD<4___PPT9 +28 PI( dI(dCC C R | n*t??Rectangle 40 bD<4___PPT9 ` I dC  bpP  |C *Group 41"bpP  | b(t??Rectangle 42+bEP D<4___PPT9 2,4-Dihydroxybenzoic acid PI( dI(dCC C R | n)t??Rectangle 43bpP D<4___PPT9 ` I dC m pbTP  |C *Group 44"pbTP  | b't??Rectangle 45b)P D<4___PPT9 +557 PI( dI(dCC C R | n0(t??Rectangle 46pbTP D<4___PPT9 ` I dC z Tb P  |C *Group 47"Tb P  | b &t??Rectangle 48b P D<4___PPT9 2,4-Dinitrophenol PI( dI(dCC C R | n&t??Rectangle 49Tb P D<4___PPT9 ` I dC k  bP  |C *Group 50" bP  | b$t??Rectangle 51 bP D<4___PPT9 ** PI( dI(dCC C R | np%t??Rectangle 52 bP D<4___PPT9 ` I dC w P p  |C *Group 53"P p  | b`#t??Rectangle 54+P E D<4___PPT9 Phloroglucinol PI( dI(dCC C R | n$t??Rectangle 55P p D<4___PPT9 ` I dC m pP T  |C *Group 56"pP T  ~| b"t??Rectangle 57P ) D<4___PPT9 +408 PI( dI(dCC C R | n"t??Rectangle 58pP T D<4___PPT9 ` I dC u TP  |C *Group 59"TP  || b t??Rectangle 60P D<4___PPT9  Benzoic acid P I( dI(d CC C R }| nP!t??Rectangle 61TP D<4___PPT9 ` I dC k  P   |C *Group 62" P   z| b@t??Rectangle 63 P  D<4___PPT9 ** PI( dI(dCC C R {| nt??Rectangle 64 P  D<4___PPT9 ` I dC v  p  |C *Group 65" p  x| bt??Rectangle 66+ E D<4___PPT9 m-Nitrophenol PI( dI(d CC C R y| nt??Rectangle 67 p D<4___PPT9 ` I dC m p T  |C *Group 68"p T  v| bt??Rectangle 69 ) D<4___PPT9 +326 PI( dI(dCC C R w| n0t??Rectangle 70p T D<4___PPT9 ` I dC t T  |C *Group 71"T  t| b t??Rectangle 72 D<4___PPT9  Tannic acid P I( dI(d CC C  R u| nt??Rectangle 73T D<4___PPT9 ` I dC l    |C *Group 74"   r| bt??Rectangle 75  D<4___PPT9 -88 PI( dI(dCC C R s| npt??Rectangle 76  D<4___PPT9 ` I dC s  p~ |C *Group 77" p~ p| b`t??Rectangle 78+ E~D<4___PPT9  Resorcinol P I( dI(d CC C  R q| nt??Rectangle 79 p~D<4___PPT9 ` I dC m p T~ |C *Group 80"p T~ n| bt??Rectangle 81 )~D<4___PPT9 +296 PI( dI(dCC C R o| nt??Rectangle 82p T~D<4___PPT9 ` I dC t T ~  |C *Group 83"T ~ l| bt??Rectangle 84 ~D<4___PPT9  Gallic acid P I( dI(d CC C  R m| nPt??Rectangle 85T ~D<4___PPT9 ` I dC l  ~ !|C *Group 86" ~ j| b@t??Rectangle 87 ~D<4___PPT9 -91 PI( dI(dCC C R k| nt??Rectangle 88 ~D<4___PPT9 ` I dC ~ ~pl "|C *Group 89"~pl h| bt??Rectangle 90+~ElD<4___PPT9 p-Hydroxybenzoic acid PI( dI(dCC C R i| nt??Rectangle 91~plD<4___PPT9 ` I dC m p~Tl #|C *Group 92"p~Tl f| bt??Rectangle 93~)lD<4___PPT9 +276 PI( dI(dCC C R g| n0t??Rectangle 94p~TlD<4___PPT9 ` I dC ~ T~ l $|C *Group 95"T~ l d| b t??Rectangle 96~ lD<4___PPT9 4-t-Butylpyrocatechol PI( dI(dCC C R e| nt??Rectangle 97T~ lD<4___PPT9 ` I dC n  ~l %|C *Group 98" ~l b| bt??Rectangle 99 ~lD<4___PPT9 -92 PI( dI(dCC C T c| ppt??Rectangle 100 ~lD<4___PPT9 ` I dC | lp& &|C ,Group 101"lp& `| d` t??Rectangle 102+lE&D<4___PPT9 o-Nitrophenol PI( dI(d CC C T a| pt??Rectangle 103lp&D<4___PPT9 ` I dC s plT& '|C ,Group 104"plT& ^| d t??Rectangle 105l)&D<4___PPT9 +115 PI( dI(dCC C T _| p t??Rectangle 106plT&D<4___PPT9 ` I dC y Tl & (|C ,Group 107"Tl & \| d t??Rectangle 108l &D<4___PPT9  Pyrogallol P I( dI(d CC C  T ]| pP t??Rectangle 109Tl &D<4___PPT9 ` I dC s  l& )|C ,Group 110" l& Z| d@ t??Rectangle 111 l&D<4___PPT9 -127 PI( dI(dCC C T [| p t??Rectangle 112 l&D<4___PPT9 ` I dC u &p *|C ,Group 113"&p X| dt??Rectangle 114+&ED<4___PPT9 Phenol PI( dI(dCC C T Y| pt??Rectangle 115&pD<4___PPT9 ` I dC r p&T +|C ,Group 116"p&T V| dt??Rectangle 117&)D<4___PPT9 +96 PI( dI(dCC C T W| p0t??Rectangle 118p&TD<4___PPT9 ` I dC w T&  ,|C ,Group 119"T&  T| d t??Rectangle 120& D<4___PPT9  Dopamine P I( dI(dCC C  T U| pt??Rectangle 121T& D<4___PPT9 ` I dC r  & -|C ,Group 122" & R| dt??Rectangle 123 &D<4___PPT9 -42 PI( dI(dCC C T S| ppt??Rectangle 124 &D<4___PPT9 ` I dC p p .|C ,Group 125"p P| d`t??Rectangle 126+ED<4___PPT9 Rutin LI dI dCC C T Q| pt??Rectangle 127pD<4___PPT9 ` I dC r pT /|C ,Group 128"pT N| dt??Rectangle 129)D<4___PPT9 +80 PI( dI(dCC C T O| pt??Rectangle 130pTD<4___PPT9 ` I dC v T  0|C ,Group 131"T  L| ds??Rectangle 132 D<4___PPT9 Aniline PI( dI(dCC C  T M| pPt??Rectangle 133T D<4___PPT9 ` I dC q   1|C ,Group 134"  J| d0 ??Rectangle 135 D<4___PPT9 ** PI( dI(dCC C T K| p ??Rectangle 136 D<4___PPT9 ` I dC w p 2|C ,Group 137"p H| dЩ ??Rectangle 138+ED<4___PPT9  Catechol P I( dI(dCC C  T I| p ??Rectangle 139pD<4___PPT9 ` I dC r pT 3|C ,Group 140"pT F| d@ ??Rectangle 141)D<4___PPT9 +73 PI( dI(dCC C T G| p  ??Rectangle 142pTD<4___PPT9 ` I dC  T  4|C ,Group 143"T  D| d` ??Rectangle 144 D<4___PPT9 p-Phenylendiamine PI( dI(dCC C T E| p ??Rectangle 145T D<4___PPT9 ` I dC q   5|C ,Group 146"  B| dP ??Rectangle 147 D<4___PPT9 ** PI( dI(dCC C T C| p ??Rectangle 148 D<4___PPT9 ` I dC  p 6|C ,Group 149"p @| dP ??Rectangle 150+ED<4___PPT9 3,4-Dihydroxybenzoic acid PI( dI(dCC C T A| p ??Rectangle 151pD<4___PPT9 ` I dC r pT 7|C ,Group 152"pT >| d ??Rectangle 153)D<4___PPT9 +69 PI( dI(dCC C T ?| p ??Rectangle 154pTD<4___PPT9 ` I dC b T  8|C ,Group 155"T t <| dp ??Rectangle 156 D<4___PPT9  BI( dI(dC C T =| pГ ??Rectangle 157T D<4___PPT9 ` I dC b   9|C ,Group 158" t :| d ??Rectangle 159 D<4___PPT9  BI( dI(dC C T ;| p ??Rectangle 160 D<4___PPT9 ` I dC T | p0 h+??Rectangle 161D<4___PPT9 ` I dC  fDW&cC3___PPT10.+fD%' = @B D' = @BA?%,( < +O%,( < +D' = @B%(D' = @B%(DD' =A@BBBB0B%(D' =1:Bvisible*o3>+B#style.visibility<*|6%(D' =-s6Bwipe(left)*<3<*|6D' = @B%(D' = @B%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*|%(D' =-s6Bwipe(left)*<3<*|+8+0+| +"m ddPPd(     x0>t0e0e?Rectangle 2"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!drs/downrev.xmlDN0DHHZ"VUUD.j)%ƁNIZ8b8Qw r׭kߞ' "yG a1atq#澔2ֆ,ƩɥEN14Rv2ϲBZl]z0P sx0=G[TǍ\WnoGwW* ϋqx9Vo12I0&U PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!drs/downrev.xmlPKH$ -   PTable 5 Parameters of regression equations and detection limits for polyphenols  Q OQ _y w  C (Group 3#"PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!IWdrs/downrev.xmlDOk@&DWA >`mȮIBaf~,VDK+-+Gs +ˤEVSm;>R{v)*(S)]VA75q1lrT24XrX(MA4 vvqmu;~_1)>szk﵂$) _@.PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!IWdrs/downrev.xmlPK,$D -%Y~ t  C (Group 4"t t~ " C (Group 5"" O `0_t??Rectangle 6+"D<4___PPT9 Organic Compounds PI( dI(dCC C P P l_t??Rectangle 7"D<4___PPT9 ` I dC y~ " C (Group 8"" M `]t??Rectangle 9"D<4___PPT9 Linear range (ng/ml) PI( dI(dCC C R N n^t??Rectangle 10"D<4___PPT9 ` I dC |  " C *Group 11" " K bp\t??Rectangle 12>\ "D<4___PPT9 Regression equation PI( dI(dCC C R L n ]t??Rectangle 13 "D<4___PPT9 ` I dC   "  C *Group 14" " I b[t??Rectangle 15 "D<4___PPT9 Correlation Coefficient l I( d I(d CC CC C R J n[t??Rectangle 16 "D<4___PPT9 ` I dC   "  C *Group 17" " G bYt??Rectangle 18* "D<4___PPT9 Detection Limit (ng/ml)  I( dI(d CC CC CC C R H n`Zt??Rectangle 19 "D<4___PPT9 ` I dC w "*  C *Group 20""* E bPXt??Rectangle 21+"*D<4___PPT9 Salicylic acid PI( dI(dCC C R F nYt??Rectangle 22"*D<4___PPT9 ` I dC q "*  C *Group 23""* C bVt??Rectangle 24"*D<4___PPT9  4 ~ 1100 P I( dI(dCC C  R D nWt??Rectangle 25"*D<4___PPT9 ` I dC  " *  C *Group 26"" * A bUt??Rectangle 27>"\ *D<4___PPT9 (lgDI=6.65 + 0.75lgC I( dI(dCCCC  R B n@Vt??Rectangle 28" *D<4___PPT9 ` I dC o  " * C *Group 29" " * ? b0Tt??Rectangle 30 " *D<4___PPT9 0.9983 PI( dI(dCC C R @ nTt??Rectangle 31 " *D<4___PPT9 ` I dC l  "* C *Group 32" "* = bRt??Rectangle 33* "*D<4___PPT9 2.5 PI( dI(dCC C R > nSt??Rectangle 34 "*D<4___PPT9 ` I dC } *~ C *Group 35"*~ ; bpQt??Rectangle 36+*~D<4___PPT9 Sulphosalicylic acid PI( dI(dCC C R < n Rt??Rectangle 37*~D<4___PPT9 ` I dC r *~ C *Group 38"*~ 9 bPt??Rectangle 39*~D<4___PPT9  40 ~ 8000 P I( dI(d CC C  R : nPt??Rectangle 40*~D<4___PPT9 ` I dC  * ~ C *Group 41"* ~ 7 bNt??Rectangle 42>*\ ~D<4___PPT9 $lgDI=6.73+0.75lgC rI( dI(dC C  R 8 n`Ot??Rectangle 43* ~D<4___PPT9 ` I dC o  * ~ C *Group 44" * ~ 5 bPMt??Rectangle 45 * ~D<4___PPT9 0.9987 PI( dI(dCC C R 6 nNt??Rectangle 46 * ~D<4___PPT9 ` I dC l  *~ C *Group 47" *~ 3 bKt??Rectangle 48* *~D<4___PPT9 7.5 PI( dI(dCC C R 4 nLt??Rectangle 49 *~D<4___PPT9 ` I dC  ~l  C *Group 50"~l  1 bJt??Rectangle 51+~l D<4___PPT9 2,4-Dihydroxybenzoic acid NI dI(dCC C R 2 n@Kt??Rectangle 52~l D<4___PPT9 ` I dC r ~l  C *Group 53"~l  / b0It??Rectangle 54~l D<4___PPT9  12 ~ 6200 P I( dI(d CC C  R 0 nIt??Rectangle 55~l D<4___PPT9 ` I dC  ~ l  C *Group 56"~ l  - bGt??Rectangle 57>~\ l D<4___PPT9 $lgDI=5.84+0.66lgC rI( dI(dC C  R . nHt??Rectangle 58~ l D<4___PPT9 ` I dC o  ~ l  C *Group 59" ~ l  + bCt??Rectangle 60 ~ l D<4___PPT9 0.9946 PI( dI(dCC C R , n Gt??Rectangle 61 ~ l D<4___PPT9 ` I dC l  ~l  C *Group 62" ~l  ) b@t??Rectangle 63* ~l D<4___PPT9 9.0 PI( dI(dCC C R * nPBt??Rectangle 64 ~l D<4___PPT9 ` I dC w l t  C *Group 65"l t  ' b?t??Rectangle 66+l t D<4___PPT9 Phloroglucinol PI( dI(dCC C R ( nCt??Rectangle 67l t D<4___PPT9 ` I dC q l t  C *Group 68"l t  % b>t??Rectangle 69l t D<4___PPT9  63 ~1000 P I( dI(dCC C  R & n`Dt??Rectangle 70l t D<4___PPT9 ` I dC  l t  C *Group 71"l t  # bEt??Rectangle 72>l \ t D<4___PPT9 $lgDI=6.42+0.76lgC xI( dI(dC C  R $ n=t??Rectangle 73l t D<4___PPT9 ` I dC o  l t  C *Group 74" l t  ! bpFt??Rectangle 75 l t D<4___PPT9 0.9960 PI( dI(dCC C R " nEt??Rectangle 76 l t D<4___PPT9 ` I dC k  l t  C *Group 77" l t   bp;t??Rectangle 78* l t D<4___PPT9 48 PI( dI(dCC C R   n +B#style.visibility<*Q%(D' =-s6Bwipe(left)*<3<*QD' = @B%(D' = @B%(D7' =4@BBBB%(D' =1:Bvisible*o3>+B#style.visibility<*%(D' =-s6Bwipe(left)*<3<*+8+0+ +"*B AACCA(    ^I d2C CC*    ?v z7 C (Group 3"z7v  # itA#??Rectangle 4Emr N[҉~  ` D<4___PPT9 ` I dC T~  C (Group 5"P B l@wt??Rectangle 6PD<4___PPT9 ` I dC n C ^wt??Text Box 7D<4___PPT9 AmRvA.I d2CC  V~ @@ C (Group 8"` P @ lut??Rectangle 9@@D<4___PPT9 ` I dC p A `vt??Text Box 10@@D<4___PPT9 AmRvB.I d2CC  B  ^??Line 11P@@J   C *Group 12"R > ntt??Rectangle 13D<4___PPT9 ` I dC ` ? `0ut??Text Box 14 D<4___PPT9 |ؚSl.I d2CC J    C *Group 15"` R < n st??Rectangle 16D<4___PPT9 ` I dC ` = `st??Text Box 17 D<4___PPT9 |ؚSl.I d2CC B   ^??Line 18PB   ^??Line 19@@B   ^??Line 20B   ^??Line 21@B  ^??Line 220B  ^??Line 23pB  ^??Line 240p0R  n ht??Rectangle 25p `D<4___PPT9 ` I dC `  `ht??Text Box 26@P `D<4___PPT9 |mThV.I d2CC B  ^??Line 27  R  n`t??Rectangle 28  `D<4___PPT9 ` I dC `  `at??Text Box 29  `D<4___PPT9 |ۏ7h.I d2CC B  ^??Line 30  B  ^??Line 31  f  f@at??Text Box 32$ D<4___PPT9 |r1g.I d2CC B  ^??Line 33 p L ` P  C *Group 34"@ R : nqt??Rectangle 35` P D<4___PPT9 ` I dC b ; `prt??Text Box 36@`  D<4___PPT9 ~T)n20 I d2C  J  P  C *Group 37"@0  R 8 n`pt??Rectangle 38 P D<4___PPT9 ` I dC ` 9 `qt??Text Box 39p  D<4___PPT9 |Ce4+0I d2CK B  ^??Line 40 B  ^??Line 41 @ @ B  ^??Line 42 B  ^??Line 43 B   ^??Line 44 R ! nbt??Rectangle 45 p ` D<4___PPT9 ` I dC B " ^??Line 46 @ B # ^??Line 47 R $ `Pct??Text Box 48 ` D<4___PPT9 nmThV I d2C B % ^??Line 49 P b & `dt??Text Box 50@`  D<4___PPT9 ~mTS^.I d2CC B ' ^??Line 51 ` R ( ndt??Rectangle 52  D<4___PPT9 ` I dC t ) ``et??Text Box 53` 0 D<4___PPT9  DADhKmhV.I d2CC  B * ^??Line 54Pp P RB + n0jt??AutoShape 55  p D<4___PPT9 ` I dC B , ^??Line 56P` P B - ^??Line 57P` ` ^ . `jt??Text Box 58 0 D<4___PPT9 z^m.I d2CC R / nkt??Rectangle 59P  D<4___PPT9 ` I dC B 0 d??Line 60 @ ` 1 `@lt??Text Box 61Pp 00 D<4___PPT9 |nIQGr.I d2CC f 2 flt??Text Box 62` Z D<4___PPT9 |AmR`l.I d2CC d 3 `mt??Text Box 63P  D<4___PPT9  IQ5u PX{.I d2CC B 4 ^??Line 64   R 5 nPnt??Rectangle 65 @ D<4___PPT9 ` I dC d 6 fot??Text Box 66 zp D<4___PPT9 zU_.I d2CC  7 `ot??Text Box 67P 7D<4___PPT9 HPLC-CL hKm|~. I d2 CC   fDW&cC3" 0n(    ^zt??Text Box 2P0ppD<4___PPT9 *Ce4+SO|vؚHemvr1-Sf[SIQhKmlDI d2CKC8     Z  ZA$ ??Object 3` p    ^zt??Text Box 4P ;D<4___PPT9 8mT7hTSm^:2.510-6g/ml. 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,dGdEc.]$KB#$ J2OPYJDw00DA94Oy``"!Ah֒G-ANtjKhq.!|$OC~||*4]w\Ycyl\Z8_FCVr{ƁRpkPC94PrPXB wK&)$ߢič\E[ Hǀxb!L1)#d{)Rf9Yd@+opna(3na(JtdXpg-YfYg^azC ɏ>oC6z3;-ϻ?8efPK!=qdrs/downrev.xmlDj1!Lw5[XF)^If L$ڧoq޶L> GiõnYc\)z5,t.c-41vjb8y-$}-Kg\Z4 vPSl߯t 4Sx?4'3I_@PK-!8[Content_Types].xmlPK-!8! /_rels/.relsPK-!hccg 7.drs/e2oDoc.xmlPK-!=qdrs/downrev.xmlPK0q   <Py "PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!ٔdrs/downrev.xmlD]K@E߅eFE)R*VqN>Hv6nۤޥ;˙/Ӊ9XV0M@V7\)mg |@Y&#yX.&7sL=yDOQABJ鋚 cWZg0*#t1I^B=k*|o<|}~Y?WzhʱgԇVMlsޠΗh-A.PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!ٔdrs/downrev.xmlPK   mSample  H( U    <| "PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!Qp,drs/downrev.xmlDMk@e M[*]E*%Gަ1 fg_ŋwyy&޵H!6 <2Pĥ W6돧([dLf ֟xIǕT*A8hrcY8qv>8CmSVdP;l8-{M~up~-rGl_q]Ǡz=mWԧ5Lv/4vQ(\/4YPK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!Qp,drs/downrev.xmlPK   5Adrenaline found (mg/ml) This method Ref. value  6H( U66    <`{ "PK![Content_Types].xml|N0 HC+jS8 @:Q۸ ??\o<7p]V޷O(I'6E=, ){Ō4>I)q7UuDހǏ)}nL"Mᴸ&g0eSA)΄2';2 WYu7{ɯΒzŘqFrj9K*(]mOlPK!Z,[ _rels/.relslj0 ``t_Pƈ[>,dgzjǎ?I'f#®Pb-\/Ƿ0Z]nLnp__3.iJV KQBiDžrL,Vʌ/7р4`ANar+m;E/'3U Aںv83/PK!| drs/downrev.xmlDMK1!f*emZ"+⥭q3]Ldn =wx^|N).Qf* E )|vy1҆/iFe "}u[F'&Dclxp]QǎB==ToW;o}]i;f{/1W .Cz+Ϩ7k lOP<_i=PK-![Content_Types].xmlPK-!Z,[ _rels/.relsPK-!| drs/downrev.xmlPK    :RSD (%) Added value (10-7 mol/L) :;H( U/  ; 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