访问量:   最后更新时间:--

张宁

博士生导师
硕士生导师
教师姓名:张宁
电子邮箱:
办公地点:苏州高等研究院亲民楼202-5
职称:特任教授
毕业院校:中国科学技术大学
所属院系:环境科学与工程系(直属)
学科:
其他联系方式

暂无内容

组内新闻
当前位置: Home > 组内新闻
2025-04-22 祝贺课题组在《Chemical Society Reviews》上发表论文!
发布时间:2025-04-22    点击次数:

祝贺课题组在《Chemical Society Reviews》上发表有关光/热催化有机分子转化综合性评估对比的指导综述论文!


Title: Modern organic transformations: heterogeneous thermocatalysis or photocatalysis?

Abstract: Organic transformation driven by heterogeneous catalysis is of crucial significance in both fundamental research and modern industrial production of fine chemicals. Thermocatalysis has offered the splendid applications due to its high activity and excellent scalability, yet still confronting the grand challenges toward the goals of high efficiency, energy-saving and sustainability. Recently, photocatalysis has emerged as a promising alternative for addressing these issues in a green and economical manner. In practice, the selection of an appropriate catalytic system is a critical factor that can influence the chemical process on multiple levels significantly. In this review, we aim to present a tutorial demonstration about the critical comparison between thermo- and photocatalytic terms for organic transformation. We begin with outlining the basic principles in thermo- and photocatalytic fundamentals, together with summarizing the general advantages and disadvantages of each. Subsequently, given the high sustainability and potentiality exhibited by the photocatalytic process, we present its representative applications including oxidation, reduction, coupling, and cleavage series. The general reaction conditions and activities observed in thermocatalysis for similar reactions are also introduced for comparison. The understandings of reaction mechanisms and the resulting regulations toward activity and selectivity are specifically discussed. Finally, future perspectives of heterogeneous photocatalytic term for the practical applications are elucidated.