Highly reversible formation and decomposition of S–S dimers driven by the migration of metal Cr in layered NaCr2/3Ti1/3S2
Hits:99
DOI number:10.1038/s41467-019-12310-6
Journal:Nature Communications
Key Words:X-RAY-ABSORPTION;POSITIVE ELECTRODE;CRYSTAL-STRUCTURE;VANADIUM SULFIDE;SULFUR;CHEMISTRY;CATHODES;SPECTROSCOPY;CHALLENGES;MOSSBAUER
Abstract:The use of anion redox reactions is gaining interest for increasing rechargeable capacities in alkaline ion batteries. Although anion redox coupling of S2- and (S-2)(2-) through dimerization of S-S in sulfides have been studied and reported, an anion redox process through electron hole formation has not been investigated to the best of our knowledge. Here, we report an O3-NaCr2/3Ti1/3S2 cathode that delivers a high reversible capacity of similar to 186 mAh g(-1) (0.95 Na) based on the cation and anion redox process. Various charge compensation mechanisms of the sulfur anionic redox process in layered NaCr2/3Ti1/3S2, which occur through the formation of disulfide-like species, the precipitation of elemental sulfur, S-S dimerization, and especially through the formation of electron holes, are investigated. Direct structural evidence for formation of electron holes and (S2)(n-) species with shortened S-S distances is obtained. These results provide valuable information for the development of materials based on the anionic redox reaction.
First Author:Tian Wang
Co-author:Guo-Xi Ren, Ji-Li Yue, Yi-Fei Mo, Xi-Qian Yu, Ming-Hui Cao, Zulipiya Shadike
Correspondence Author:Pan Liu,Xiaosong Liu,Zheng-Wen Fu
Document Code:4458
Volume:10
ISSN No.:2041-1723
Translation or Not:no
Date of Publication:2019-10-01
Links to published journals:https://www.nature.com/articles/s41467-019-12310-6
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