2. 酶催化有机合成
学术成果:
1. Sun, S.-Z.; Hu, J.; Shankel, S.; Lambert, T. H.; *, Fors, B. P.* Hydrogen bond donor controlled stereoselective cationic polymerization of 2,3-dihydrofuran. (Submitted).
2. Sun, S.-Z.; Nicholls, B.T.; Bain, D.; Qiao, T.; Page, C. G.; Musser, A. J.; Hyster,T. K.* Enantioselective decarboxylative alkylation using synergistic photoenzymatic catalysis. Nat. Catal, 2024, 7, 35-42.
3. Sun, S.-Z.;† Cai, Y.-M.;† Zhang, D.-L.; Wang, J.-B.; Yao, H.-Q.; Rui, X.-Y.; Martin, R.; Shang, M.* Enantioselective deaminative alkylation of amino acid derivatives with unactivated olefins. J. Am. Chem. Soc. 2022, 144, 1130-1137. (†共同一作)
4. Sun, S.-Z.;† Talavera, L.;† Spieb, P.; Day, C. S.; Martin, R.* sp3 bis-organometallic reagents via catalytic 1,1-difunctionalization of unactivated olefins. Angew. Chem. Int. Ed. 2021, 60, 11740-11744. (†共同一作)
5. Sun, S.-Z.;† Duan, Y.;† Mega, R. S.; Somerville, R. J.; Martin, R.* Site-selective 1,2-dicarbofunctionalization of vinyl boronates via dual catalysis. Angew. Chem. Int. Ed. 2020, 59, 4370-4374. (†共同一作)
6. Sun, S.-Z.; Romano, C.; Martin, R.* Site-selective catalytic deaminative alkylation of unactivated olefins. J. Am. Chem. Soc. 2019, 141, 16197-16201.
7. Sun, S.-Z.; Borjesson, M.; Martin-Montero, R.; Martin, R.* Site-selective Ni-catalyzed reductive coupling of alpha-haloboranes with unactivated olefins. J. Am. Chem. Soc. 2018, 140, 12765-12769.
8. Sun, S.-Z.; Martin, R.* Nickel-catalyzed umpolung arylation of ambiphilic-bromoalkyl boronic esters. Angew. Chem. Int. Ed. 2018, 57, 3622-3625.
9. van Gemmeren, M.;† Borjesson, M.;† Tortajada, A.;† Sun, S.-Z.;† Martin, R.* Switchable site-selective catalytic carboxylation of allylic alcohols with CO2. Angew. Chem. Int. Ed. 2017, 56, 6558-6562. (†共同一作)
10. Sun, S.-Z.;†Shang, M.;† Xu, H.; Cheng, T.-J.; Dai, H.-X.* Copper mediated C(sp2)-H amination and hydroxylation of phosphinamides. Chem. Commun., 2020, 56, 1444-1447. (†共同一作)
11. Sun, S.-Z.; Xu, H.; Dai, H.-X.* Copper-catalyzed a-selective C–H trifluoromethylation of acrylamides with TMSCF3. Chin. Chem. Lett. 2019, 30, 969-972.
12. Sun, S.-Z.; Shang, M.; Wang, H.-L.; Lin, H.-X.;* Dai, H.-X.;* Yu, J.-Q.* Cu(II)-mediated C(sp2)–H hydroxylation. J. Org. Chem., 2015, 80, 8843-8848.